A unique 3D ultramicroporous triptycene-based polyimide framework for efficient gas sorption applications

Handle URI:
http://hdl.handle.net/10754/622372
Title:
A unique 3D ultramicroporous triptycene-based polyimide framework for efficient gas sorption applications
Authors:
Ghanem, Bader ( 0000-0002-2044-2434 ) ; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Wang, Yingge; Zhao, Yunfeng; Han, Yu ( 0000-0003-1462-1118 ) ; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Pinnau, Ingo ( 0000-0003-3040-9088 )
Abstract:
A novel 3D ultramicroporous triptycene-based polyimide framework with high surface area (1050 m2 g−1) and thermal stability was synthesized. It exhibits relatively high CO2 (3.4 mmol g−1 at 273 K and 1 bar), H2 (7 mmol g−1 at 77 K and 1 bar), and olefin sorption capacity, good CO2/N2 (45) and CO2/CH4 (9.6) selectivity at 273 K and 1 bar, as well as promising C2H4/CH4 and C3H6/CH4 selectivities at 298 K, making it a potential candidate for CO2 capture, H2 storage, and hydrocarbon gas separation applications.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Chemical and Biological Engineering Program; Physical Sciences and Engineering (PSE) Division
Citation:
Ghanem B, Belmabkhout Y, Wang Y, Zhao Y, Han Y, et al. (2016) A unique 3D ultramicroporous triptycene-based polyimide framework for efficient gas sorption applications. RSC Adv 6: 97560–97565. Available: http://dx.doi.org/10.1039/c6ra21388j.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
RSC Adv.
Issue Date:
3-Oct-2016
DOI:
10.1039/c6ra21388j
Type:
Article
ISSN:
2046-2069
Sponsors:
The research reported in this publication was supported by funding from King Abdullah University of Science and Technology (KAUST).
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2016/RA/C6RA21388J
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Chemical and Biological Engineering Program

Full metadata record

DC FieldValue Language
dc.contributor.authorGhanem, Baderen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorWang, Yinggeen
dc.contributor.authorZhao, Yunfengen
dc.contributor.authorHan, Yuen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorPinnau, Ingoen
dc.date.accessioned2017-01-02T09:28:27Z-
dc.date.available2017-01-02T09:28:27Z-
dc.date.issued2016-10-03en
dc.identifier.citationGhanem B, Belmabkhout Y, Wang Y, Zhao Y, Han Y, et al. (2016) A unique 3D ultramicroporous triptycene-based polyimide framework for efficient gas sorption applications. RSC Adv 6: 97560–97565. Available: http://dx.doi.org/10.1039/c6ra21388j.en
dc.identifier.issn2046-2069en
dc.identifier.doi10.1039/c6ra21388jen
dc.identifier.urihttp://hdl.handle.net/10754/622372-
dc.description.abstractA novel 3D ultramicroporous triptycene-based polyimide framework with high surface area (1050 m2 g−1) and thermal stability was synthesized. It exhibits relatively high CO2 (3.4 mmol g−1 at 273 K and 1 bar), H2 (7 mmol g−1 at 77 K and 1 bar), and olefin sorption capacity, good CO2/N2 (45) and CO2/CH4 (9.6) selectivity at 273 K and 1 bar, as well as promising C2H4/CH4 and C3H6/CH4 selectivities at 298 K, making it a potential candidate for CO2 capture, H2 storage, and hydrocarbon gas separation applications.en
dc.description.sponsorshipThe research reported in this publication was supported by funding from King Abdullah University of Science and Technology (KAUST).en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2016/RA/C6RA21388Jen
dc.titleA unique 3D ultramicroporous triptycene-based polyimide framework for efficient gas sorption applicationsen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentChemical and Biological Engineering Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalRSC Adv.en
kaust.authorGhanem, Baderen
kaust.authorBelmabkhout, Youssefen
kaust.authorWang, Yinggeen
kaust.authorZhao, Yunfengen
kaust.authorHan, Yuen
kaust.authorEddaoudi, Mohameden
kaust.authorPinnau, Ingoen
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