Star-Branched Polymers (Star Polymers)

Handle URI:
http://hdl.handle.net/10754/622253
Title:
Star-Branched Polymers (Star Polymers)
Authors:
Hirao, Akira; Hayashi, Mayumi; Ito, Shotaro; Goseki, Raita; Higashihara, Tomoya; Hadjichristidis, Nikolaos ( 0000-0003-1442-1714 )
Abstract:
The synthesis of well-defined regular and asymmetric mixed arm (hereinafter miktoarm) star-branched polymers by the living anionic polymerization is reviewed in this chapter. In particular, much attention is being devoted to the synthetic development of miktoarm star polymers since 2000. At the present time, the almost all types of multiarmed and multicomponent miktoarm star polymers have become feasible by using recently developed iterative strategy. For example, the following well-defined stars have been successfully synthesized: 3-arm ABC, 4-arm ABCD, 5-arm ABCDE, 6-arm ABCDEF, 7-arm ABCDEFG, 6-arm ABC, 9-arm ABC, 12-arm ABC, 13-arm ABCD, 9-arm AB, 17-arm AB, 33-arm AB, 7-arm ABC, 15-arm ABCD, and 31-arm ABCDE miktoarm star polymers, most of which are quite new and difficult to synthesize by the end of the 1990s. Several new specialty functional star polymers composed of vinyl polymer segments and rigid rodlike poly(acetylene) arms, helical polypeptide, or helical poly(hexyl isocyanate) arms are introduced.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
Hirao A, Hayashi M, Ito S, Goseki R, Higashihara T, et al. (2015) Star-Branched Polymers (Star Polymers). Anionic Polymerization: 659–718. Available: http://dx.doi.org/10.1007/978-4-431-54186-8_14.
Publisher:
Springer Science + Business Media
Journal:
Anionic Polymerization
Issue Date:
1-Sep-2015
DOI:
10.1007/978-4-431-54186-8_14
Type:
Book Chapter
Appears in Collections:
Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC); Book Chapters

Full metadata record

DC FieldValue Language
dc.contributor.authorHirao, Akiraen
dc.contributor.authorHayashi, Mayumien
dc.contributor.authorIto, Shotaroen
dc.contributor.authorGoseki, Raitaen
dc.contributor.authorHigashihara, Tomoyaen
dc.contributor.authorHadjichristidis, Nikolaosen
dc.date.accessioned2017-01-02T08:42:40Z-
dc.date.available2017-01-02T08:42:40Z-
dc.date.issued2015-09-01en
dc.identifier.citationHirao A, Hayashi M, Ito S, Goseki R, Higashihara T, et al. (2015) Star-Branched Polymers (Star Polymers). Anionic Polymerization: 659–718. Available: http://dx.doi.org/10.1007/978-4-431-54186-8_14.en
dc.identifier.doi10.1007/978-4-431-54186-8_14en
dc.identifier.urihttp://hdl.handle.net/10754/622253-
dc.description.abstractThe synthesis of well-defined regular and asymmetric mixed arm (hereinafter miktoarm) star-branched polymers by the living anionic polymerization is reviewed in this chapter. In particular, much attention is being devoted to the synthetic development of miktoarm star polymers since 2000. At the present time, the almost all types of multiarmed and multicomponent miktoarm star polymers have become feasible by using recently developed iterative strategy. For example, the following well-defined stars have been successfully synthesized: 3-arm ABC, 4-arm ABCD, 5-arm ABCDE, 6-arm ABCDEF, 7-arm ABCDEFG, 6-arm ABC, 9-arm ABC, 12-arm ABC, 13-arm ABCD, 9-arm AB, 17-arm AB, 33-arm AB, 7-arm ABC, 15-arm ABCD, and 31-arm ABCDE miktoarm star polymers, most of which are quite new and difficult to synthesize by the end of the 1990s. Several new specialty functional star polymers composed of vinyl polymer segments and rigid rodlike poly(acetylene) arms, helical polypeptide, or helical poly(hexyl isocyanate) arms are introduced.en
dc.publisherSpringer Science + Business Mediaen
dc.subjectAsymmetric star polymeren
dc.subjectIterative strategyen
dc.subjectLiving anionic polymerizationen
dc.subjectMiktoarm star polymeren
dc.subjectMulticomponent and multiarmed star polymeren
dc.subjectRegular star polymeren
dc.subjectStar polymeren
dc.subjectμ-Star polymeren
dc.titleStar-Branched Polymers (Star Polymers)en
dc.typeBook Chapteren
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalAnionic Polymerizationen
dc.contributor.institutionPolymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1, Ohokayama, Meguro-ku, Tokyo, Japanen
dc.contributor.institutionInstitute of Polymer Science and Engineering, National Taiwan University, No.1, Sec.4, Roosevelt Road, Taipei, Taiwanen
dc.contributor.institutionCollege of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren Ai Road, Suzhou Industrial Park, Suzhou, Chinaen
dc.contributor.institutionDepartment of Polymer Science and Engineering, iFront Leading Doctoral Graduate School Program, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata, Japanen
dc.contributor.institutionJapan Science and Technology Agency (JST), 4-1-8, Honcho, Kawaguchi, Saitama, Japanen
kaust.authorHadjichristidis, Nikolaosen
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