Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants

Handle URI:
http://hdl.handle.net/10754/622072
Title:
Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants
Authors:
Fabry, David C.; Rueping, Magnus ( 0000-0003-4580-5227 )
Abstract:
ConspectusThe development of efficient catalytic systems for direct aromatic C-H bond functionalization is a long-desired goal of chemists, because these protocols provide environmental friendly and waste-reducing alternatives to classical methodologies for C-C and C-heteroatom bond formation. A key challenge for these transformations is the reoxidation of the in situ generated metal hydride or low-valent metal complexes of the primary catalytic bond forming cycle. To complete the catalytic cycle and to regenerate the C-H activation catalyst, (super)stoichiometric amounts of Cu(II) or Ag(I) salts have often been applied. Recently,
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Fabry DC, Rueping M (2016) Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants. Accounts of Chemical Research 49: 1969–1979. Available: http://dx.doi.org/10.1021/acs.accounts.6b00275.
Publisher:
American Chemical Society (ACS)
Journal:
Accounts of Chemical Research
Issue Date:
24-Aug-2016
DOI:
10.1021/acs.accounts.6b00275
Type:
Article
ISSN:
0001-4842; 1520-4898
Sponsors:
The research leading to the results reported has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement No. 617044 (SunCatChem).
Additional Links:
http://pubs.acs.org/doi/abs/10.1021/acs.accounts.6b00275
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorFabry, David C.en
dc.contributor.authorRueping, Magnusen
dc.date.accessioned2016-12-26T13:42:26Z-
dc.date.available2016-12-26T13:42:26Z-
dc.date.issued2016-08-24en
dc.identifier.citationFabry DC, Rueping M (2016) Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants. Accounts of Chemical Research 49: 1969–1979. Available: http://dx.doi.org/10.1021/acs.accounts.6b00275.en
dc.identifier.issn0001-4842en
dc.identifier.issn1520-4898en
dc.identifier.doi10.1021/acs.accounts.6b00275en
dc.identifier.urihttp://hdl.handle.net/10754/622072-
dc.description.abstractConspectusThe development of efficient catalytic systems for direct aromatic C-H bond functionalization is a long-desired goal of chemists, because these protocols provide environmental friendly and waste-reducing alternatives to classical methodologies for C-C and C-heteroatom bond formation. A key challenge for these transformations is the reoxidation of the in situ generated metal hydride or low-valent metal complexes of the primary catalytic bond forming cycle. To complete the catalytic cycle and to regenerate the C-H activation catalyst, (super)stoichiometric amounts of Cu(II) or Ag(I) salts have often been applied. Recently,en
dc.description.sponsorshipThe research leading to the results reported has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement No. 617044 (SunCatChem).en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/acs.accounts.6b00275en
dc.rightsThis is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.en
dc.rights.urihttp://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.htmlen
dc.titleMerging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidantsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalAccounts of Chemical Researchen
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionInstitute of Organic Chemistry, RWTH, Aachen University, Landoltweg 1, Aachen, Germanyen
kaust.authorRueping, Magnusen
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