Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide

Handle URI:
http://hdl.handle.net/10754/622059
Title:
Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide
Authors:
Haque, Mohammed; Davaasuren, Bambar ( 0000-0002-0270-3426 ) ; Rothenberger, Alexander; Wu, Tao ( 0000-0003-0845-4827 )
Abstract:
The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12)Å. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.
KAUST Department:
Physical Sciences and Engineering (PSE) Division
Citation:
Haque MA, Davaasuren B, Rothenberger A, Wu T (2016) Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide. Acta Crystallographica Section E Crystallographic Communications 72: 1791–1793. Available: http://dx.doi.org/10.1107/S2056989016017904.
Publisher:
International Union of Crystallography (IUCr)
Journal:
Acta Crystallographica Section E Crystallographic Communications
Issue Date:
15-Nov-2016
DOI:
10.1107/S2056989016017904
Type:
Article
ISSN:
2056-9890
Sponsors:
This work was supported by the King Abdullah University of Science and Technology (KAUST).
Is Supplemented By:
Haque, M. A., Davaasuren, B., Rothenberger, A., & Wu, T. (2016). CCDC 1515632: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1mw4c0; DOI:10.5517/ccdc.csd.cc1mw4c0; HANDLE:http://hdl.handle.net/10754/624597
Additional Links:
http://scripts.iucr.org/cgi-bin/paper?S2056989016017904
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorHaque, Mohammeden
dc.contributor.authorDavaasuren, Bambaren
dc.contributor.authorRothenberger, Alexanderen
dc.contributor.authorWu, Taoen
dc.date.accessioned2016-12-22T13:34:56Z-
dc.date.available2016-12-22T13:34:56Z-
dc.date.issued2016-11-15en
dc.identifier.citationHaque MA, Davaasuren B, Rothenberger A, Wu T (2016) Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide. Acta Crystallographica Section E Crystallographic Communications 72: 1791–1793. Available: http://dx.doi.org/10.1107/S2056989016017904.en
dc.identifier.issn2056-9890en
dc.identifier.doi10.1107/S2056989016017904en
dc.identifier.urihttp://hdl.handle.net/10754/622059-
dc.description.abstractThe title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12)Å. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.en
dc.description.sponsorshipThis work was supported by the King Abdullah University of Science and Technology (KAUST).en
dc.publisherInternational Union of Crystallography (IUCr)en
dc.relation.urlhttp://scripts.iucr.org/cgi-bin/paper?S2056989016017904en
dc.rightsArchived with thanks to Acta Crystallographica Section E: Crystallographic Communications. Under the Creative Commons Attribution Licenseen
dc.subjectcrystal structureen
dc.subjectisotypismen
dc.subjectoctahedral coordinationen
dc.subjecttetraiodideen
dc.titleCrystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodideen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalActa Crystallographica Section E Crystallographic Communicationsen
dc.eprint.versionPublisher's Version/PDFen
kaust.authorHaque, Mohammeden
kaust.authorDavaasuren, Bambaren
kaust.authorRothenberger, Alexanderen
kaust.authorWu, Taoen
dc.relation.isSupplementedByHaque, M. A., Davaasuren, B., Rothenberger, A., & Wu, T. (2016). CCDC 1515632: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1mw4c0en
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.cc1mw4c0en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624597en
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