Highly Efficient Electrocatalysts for Oxygen Reduction Reaction Based on 1D Ternary Doped Porous Carbons Derived from Carbon Nanotube Directed Conjugated Microporous Polymers

Handle URI:
http://hdl.handle.net/10754/621787
Title:
Highly Efficient Electrocatalysts for Oxygen Reduction Reaction Based on 1D Ternary Doped Porous Carbons Derived from Carbon Nanotube Directed Conjugated Microporous Polymers
Authors:
He, Yafei; Gehrig, Dominik; Zhang, Fan; Lu, Chenbao; Zhang, Chao; Cai, Ming; Wang, Yuanyuan; Laquai, Frederic ( 0000-0002-5887-6158 ) ; Zhuang, Xiaodong; Feng, Xinliang
Abstract:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.One-dimensional (1D) porous materials have shown great potential for gas storage and separation, sensing, energy storage, and conversion. However, the controlled approach for preparation of 1D porous materials, especially porous organic materials, still remains a great challenge due to the poor dispersibility and solution processability of the porous materials. Here, carbon nanotube (CNT) templated 1D conjugated microporous polymers (CMPs) are prepared using a layer-by-layer method. As-prepared CMPs possess high specific surface areas of up to 623 m2 g-1 and exhibit strong electronic interactions between p-type CMPs and n-type CNTs. The CMPs are used as precursors to produce heteroatom-doped 1D porous carbons through direct pyrolysis. As-produced ternary heteroatom-doped (B/N/S) 1D porous carbons possess high specific surface areas of up to 750 m2 g-1, hierarchical porous structures, and excellent electrochemical-catalytic performance for oxygen reduction reaction. Both of the diffusion-limited current density (4.4 mA cm-2) and electron transfer number (n = 3.8) for three-layered 1D porous carbons are superior to those for random 1D porous carbon. These results demonstrate that layered and core-shell type 1D CMPs and related heteroatom-doped 1D porous carbons can be rationally designed and controlled prepared for high performance energy-related applications.
KAUST Department:
Solar and Photovoltaic Engineering Research Center (SPERC)
Citation:
He Y, Gehrig D, Zhang F, Lu C, Zhang C, et al. (2016) Highly Efficient Electrocatalysts for Oxygen Reduction Reaction Based on 1D Ternary Doped Porous Carbons Derived from Carbon Nanotube Directed Conjugated Microporous Polymers. Advanced Functional Materials. Available: http://dx.doi.org/10.1002/adfm.201603693.
Publisher:
Wiley-Blackwell
Journal:
Advanced Functional Materials
Issue Date:
11-Oct-2016
DOI:
10.1002/adfm.201603693
Type:
Article
ISSN:
1616-301X
Sponsors:
Deutsche Forschungsgemeinschaft; Max-Planck-Gesellschaft; European Research Council; National Natural Science Foundation of China[61306018, 51403126]; 973 Programs of China[2012CB933400, 2013CBA01602]; EU Graphene Flagship; Max Planck Research Group of Organic Optoelectronics
Appears in Collections:
Articles; Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorHe, Yafeien
dc.contributor.authorGehrig, Dominiken
dc.contributor.authorZhang, Fanen
dc.contributor.authorLu, Chenbaoen
dc.contributor.authorZhang, Chaoen
dc.contributor.authorCai, Mingen
dc.contributor.authorWang, Yuanyuanen
dc.contributor.authorLaquai, Fredericen
dc.contributor.authorZhuang, Xiaodongen
dc.contributor.authorFeng, Xinliangen
dc.date.accessioned2016-11-03T13:24:58Z-
dc.date.available2016-11-03T13:24:58Z-
dc.date.issued2016-10-11en
dc.identifier.citationHe Y, Gehrig D, Zhang F, Lu C, Zhang C, et al. (2016) Highly Efficient Electrocatalysts for Oxygen Reduction Reaction Based on 1D Ternary Doped Porous Carbons Derived from Carbon Nanotube Directed Conjugated Microporous Polymers. Advanced Functional Materials. Available: http://dx.doi.org/10.1002/adfm.201603693.en
dc.identifier.issn1616-301Xen
dc.identifier.doi10.1002/adfm.201603693en
dc.identifier.urihttp://hdl.handle.net/10754/621787-
dc.description.abstract© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.One-dimensional (1D) porous materials have shown great potential for gas storage and separation, sensing, energy storage, and conversion. However, the controlled approach for preparation of 1D porous materials, especially porous organic materials, still remains a great challenge due to the poor dispersibility and solution processability of the porous materials. Here, carbon nanotube (CNT) templated 1D conjugated microporous polymers (CMPs) are prepared using a layer-by-layer method. As-prepared CMPs possess high specific surface areas of up to 623 m2 g-1 and exhibit strong electronic interactions between p-type CMPs and n-type CNTs. The CMPs are used as precursors to produce heteroatom-doped 1D porous carbons through direct pyrolysis. As-produced ternary heteroatom-doped (B/N/S) 1D porous carbons possess high specific surface areas of up to 750 m2 g-1, hierarchical porous structures, and excellent electrochemical-catalytic performance for oxygen reduction reaction. Both of the diffusion-limited current density (4.4 mA cm-2) and electron transfer number (n = 3.8) for three-layered 1D porous carbons are superior to those for random 1D porous carbon. These results demonstrate that layered and core-shell type 1D CMPs and related heteroatom-doped 1D porous carbons can be rationally designed and controlled prepared for high performance energy-related applications.en
dc.description.sponsorshipDeutsche Forschungsgemeinschaften
dc.description.sponsorshipMax-Planck-Gesellschaften
dc.description.sponsorshipEuropean Research Councilen
dc.description.sponsorshipNational Natural Science Foundation of China[61306018, 51403126]en
dc.description.sponsorship973 Programs of China[2012CB933400, 2013CBA01602]en
dc.description.sponsorshipEU Graphene Flagshipen
dc.description.sponsorshipMax Planck Research Group of Organic Optoelectronicsen
dc.publisherWiley-Blackwellen
dc.subject1D materialsen
dc.subjectConjugated microporous polymersen
dc.subjectLayer-by-layer methodsen
dc.subjectOxygen reduction reactionen
dc.subjectPorous carbonen
dc.titleHighly Efficient Electrocatalysts for Oxygen Reduction Reaction Based on 1D Ternary Doped Porous Carbons Derived from Carbon Nanotube Directed Conjugated Microporous Polymersen
dc.typeArticleen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.identifier.journalAdvanced Functional Materialsen
dc.contributor.institutionState Key Laboratory of Metal Matrix Composites; Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing; School of Chemistry and Chemical Engineering; Shanghai Jiao Tong University; 200240 Shanghai P. R. Chinaen
dc.contributor.institutionMax Planck Research Group for Organic Optoelectronics; Max Planck Institute for Polymer Research; Ackermannweg 10 Mainz 55128 Germanyen
dc.contributor.institutionState Key Lab of Inorganic Synthesis and Preparative Chemistry; College of Chemistry; Jilin University; Changchun 130012 P. R. Chinaen
dc.contributor.institutionCenter for Advancing Electronics Dresden (cfaed) and Department of Chemistry and Food Chemistry; Technische Universität Dresden; Mommsenstrasse 4 Dresden 01062 Germanyen
kaust.authorLaquai, Fredericen
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