Influence of phosphorous addition on Bi3Mo2Fe1 oxide catalysts for the oxidative dehydrogenation of 1-butene

Handle URI:
http://hdl.handle.net/10754/621700
Title:
Influence of phosphorous addition on Bi3Mo2Fe1 oxide catalysts for the oxidative dehydrogenation of 1-butene
Authors:
Park, Jung-Hyun ( 0000-0002-3714-2251 ) ; Shin, Chae-Ho
Abstract:
Bi3Mo2Fe1Px oxide catalysts were prepared by a co-precipitation method and the influence of phosphorous content on the catalytic performance in the oxidative dehydrogenation of 1-butene was investigated. The addition of phosphorous up to 0.4mole ratio to Bi3Mo2Fe1 oxide catalyst led to an increase in the catalytic performance; however, a higher phosphorous content (above P=0.4) led to a decrease of conversion. Of the tested catalysts, Bi3Mo2Fe1P0.4 oxide catalyst exhibited the highest catalytic performance. Characterization results showed that the catalytic performance was related to the quantity of a π-allylic intermediate, facile desorption behavior of adsorbed intermediates and ability for re-oxidation of catalysts. © 2015 Korean Institute of Chemical Engineers, Seoul, Korea
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
Park J-H, Shin C-H (2016) Influence of phosphorous addition on Bi3Mo2Fe1 oxide catalysts for the oxidative dehydrogenation of 1-butene. Korean J Chem Eng 33: 823–830. Available: http://dx.doi.org/10.1007/s11814-015-0239-z.
Publisher:
Springer Science + Business Media
Journal:
Korean Journal of Chemical Engineering
Issue Date:
22-Jan-2016
DOI:
10.1007/s11814-015-0239-z
Type:
Article
ISSN:
0256-1115; 1975-7220
Sponsors:
This work was supported by the Energy Efficiency and Resources of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) granted financial resource from the Ministry of Trade, Industry and Energy, Republic of Korea (No. 2014021194).
Additional Links:
article/10.1007/s11814-015-0239-z
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorPark, Jung-Hyunen
dc.contributor.authorShin, Chae-Hoen
dc.date.accessioned2016-11-03T13:23:03Z-
dc.date.available2016-11-03T13:23:03Z-
dc.date.issued2016-01-22en
dc.identifier.citationPark J-H, Shin C-H (2016) Influence of phosphorous addition on Bi3Mo2Fe1 oxide catalysts for the oxidative dehydrogenation of 1-butene. Korean J Chem Eng 33: 823–830. Available: http://dx.doi.org/10.1007/s11814-015-0239-z.en
dc.identifier.issn0256-1115en
dc.identifier.issn1975-7220en
dc.identifier.doi10.1007/s11814-015-0239-zen
dc.identifier.urihttp://hdl.handle.net/10754/621700-
dc.description.abstractBi3Mo2Fe1Px oxide catalysts were prepared by a co-precipitation method and the influence of phosphorous content on the catalytic performance in the oxidative dehydrogenation of 1-butene was investigated. The addition of phosphorous up to 0.4mole ratio to Bi3Mo2Fe1 oxide catalyst led to an increase in the catalytic performance; however, a higher phosphorous content (above P=0.4) led to a decrease of conversion. Of the tested catalysts, Bi3Mo2Fe1P0.4 oxide catalyst exhibited the highest catalytic performance. Characterization results showed that the catalytic performance was related to the quantity of a π-allylic intermediate, facile desorption behavior of adsorbed intermediates and ability for re-oxidation of catalysts. © 2015 Korean Institute of Chemical Engineers, Seoul, Koreaen
dc.description.sponsorshipThis work was supported by the Energy Efficiency and Resources of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) granted financial resource from the Ministry of Trade, Industry and Energy, Republic of Korea (No. 2014021194).en
dc.publisherSpringer Science + Business Mediaen
dc.relation.urlarticle/10.1007/s11814-015-0239-zen
dc.subject1-C4H8-temperature-programmed Desorptionen
dc.subjectBi3Mo2Fe1Px Oxide Catalysten
dc.subjectButadieneen
dc.subjectOxidative Dehydrogenationen
dc.subjectTemperature-programmed Re-oxidationen
dc.titleInfluence of phosphorous addition on Bi3Mo2Fe1 oxide catalysts for the oxidative dehydrogenation of 1-buteneen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalKorean Journal of Chemical Engineeringen
dc.contributor.institutionDepartment of Chemical Engineering, Chungbuk National University, Chungbuk, South Koreaen
kaust.authorPark, Jung-Hyunen
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