Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide

Handle URI:
http://hdl.handle.net/10754/621694
Title:
Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide
Authors:
Wang, De ( 0000-0002-3737-6621 ) ; Zhang, Zhen; Hadjichristidis, Nikolaos ( 0000-0003-1442-1714 )
Abstract:
A novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time. (Chemical Equation Presented). © 2016 American Chemical Society.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Polymer Synthesis Laboratory
Citation:
Wang D, Zhang Z, Hadjichristidis N (2016) Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide. ACS Macro Letters 5: 387–390. Available: http://dx.doi.org/10.1021/acsmacrolett.6b00082.
Publisher:
American Chemical Society (ACS)
Journal:
ACS Macro Letters
Issue Date:
1-Mar-2016
DOI:
10.1021/acsmacrolett.6b00082
Type:
Article
ISSN:
2161-1653; 2161-1653
Sponsors:
Research reported in this publication was supported by the King Abdullah University of Science and Technology.
Additional Links:
http://pubs.acs.org/doi/abs/10.1021/acsmacrolett.6b00082
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Deen
dc.contributor.authorZhang, Zhenen
dc.contributor.authorHadjichristidis, Nikolaosen
dc.date.accessioned2016-11-03T13:22:55Z-
dc.date.available2016-11-03T13:22:55Z-
dc.date.issued2016-03-01en
dc.identifier.citationWang D, Zhang Z, Hadjichristidis N (2016) Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide. ACS Macro Letters 5: 387–390. Available: http://dx.doi.org/10.1021/acsmacrolett.6b00082.en
dc.identifier.issn2161-1653en
dc.identifier.issn2161-1653en
dc.identifier.doi10.1021/acsmacrolett.6b00082en
dc.identifier.urihttp://hdl.handle.net/10754/621694-
dc.description.abstractA novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time. (Chemical Equation Presented). © 2016 American Chemical Society.en
dc.description.sponsorshipResearch reported in this publication was supported by the King Abdullah University of Science and Technology.en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/acsmacrolett.6b00082en
dc.titleBoron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylideen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentPolymer Synthesis Laboratoryen
dc.identifier.journalACS Macro Lettersen
kaust.authorWang, Deen
kaust.authorZhang, Zhenen
kaust.authorHadjichristidis, Nikolaosen
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