Trifluoromethylselenolation of Aryldiazonium Salts: A Mild and Convenient Copper-Catalyzed Procedure for the Introduction of the SeCF3Group

Handle URI:
http://hdl.handle.net/10754/621686
Title:
Trifluoromethylselenolation of Aryldiazonium Salts: A Mild and Convenient Copper-Catalyzed Procedure for the Introduction of the SeCF3Group
Authors:
Nikolaienko, Pavlo; Rueping, Magnus ( 0000-0003-4580-5227 )
Abstract:
The straightforward introduction of the trifluoromethylseleno group into aromatic and heteroaromatic compounds is accomplished by the utilization of readily available aryldiazonium tetrafluoroborates, potassium selenocyanate, and Ruppert-Prakash reagent. The reaction tolerates a wide range of aromatic and heteroaromatic diazonium salts and is also amenable to the synthesis of pentafluoroethyl selenoethers. Furthermore, the methodology can be applied directly starting from anilines. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Nikolaienko P, Rueping M (2016) Trifluoromethylselenolation of Aryldiazonium Salts: A Mild and Convenient Copper-Catalyzed Procedure for the Introduction of the SeCF3Group. Chem Eur J 22: 2620–2623. Available: http://dx.doi.org/10.1002/chem.201504601.
Publisher:
Wiley-Blackwell
Journal:
Chemistry - A European Journal
Issue Date:
21-Jan-2016
DOI:
10.1002/chem.201504601
Type:
Article
ISSN:
0947-6539
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/chem.201504601/full
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorNikolaienko, Pavloen
dc.contributor.authorRueping, Magnusen
dc.date.accessioned2016-11-03T13:22:45Z-
dc.date.available2016-11-03T13:22:45Z-
dc.date.issued2016-01-21en
dc.identifier.citationNikolaienko P, Rueping M (2016) Trifluoromethylselenolation of Aryldiazonium Salts: A Mild and Convenient Copper-Catalyzed Procedure for the Introduction of the SeCF3Group. Chem Eur J 22: 2620–2623. Available: http://dx.doi.org/10.1002/chem.201504601.en
dc.identifier.issn0947-6539en
dc.identifier.doi10.1002/chem.201504601en
dc.identifier.urihttp://hdl.handle.net/10754/621686-
dc.description.abstractThe straightforward introduction of the trifluoromethylseleno group into aromatic and heteroaromatic compounds is accomplished by the utilization of readily available aryldiazonium tetrafluoroborates, potassium selenocyanate, and Ruppert-Prakash reagent. The reaction tolerates a wide range of aromatic and heteroaromatic diazonium salts and is also amenable to the synthesis of pentafluoroethyl selenoethers. Furthermore, the methodology can be applied directly starting from anilines. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/chem.201504601/fullen
dc.subjectanilinesen
dc.subjectcopperen
dc.subjectdiazonium saltsen
dc.subjectfluorineen
dc.subjectorganic chemistryen
dc.titleTrifluoromethylselenolation of Aryldiazonium Salts: A Mild and Convenient Copper-Catalyzed Procedure for the Introduction of the SeCF3Groupen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalChemistry - A European Journalen
dc.contributor.institutionInstitute of Organic Chemistry; RWTH Aachen University; Landoltweg 1 52074 Aachen Germanyen
kaust.authorRueping, Magnusen
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