Nickel-Catalyzed C sp2 –C sp3 Cross-Coupling via C–O Bond Activation

Handle URI:
http://hdl.handle.net/10754/621676
Title:
Nickel-Catalyzed C sp2 –C sp3 Cross-Coupling via C–O Bond Activation
Authors:
Guo, Lin; Hsiao, Chien-Chi; Yue, Huifeng; Liu, Xiangqian; Rueping, Magnus ( 0000-0003-4580-5227 )
Abstract:
A new and efficient nickel-catalyzed alkylation of CAr-O electrophiles with B-alkyl-9-BBNs is described. The transformation is characterized by its functional group tolerance and provides a practical and versatile access to various Csp2-Csp3 bonds through Csp2-O substitution, without the restriction of β-hydride elimination. Moreover, the advantage of the newly developed method was demonstrated in a selective and sequential C-O bond activation process. © 2016 American Chemical Society.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Guo L, Hsiao C-C, Yue H, Liu X, Rueping M (2016) Nickel-Catalyzed C sp2 –C sp3 Cross-Coupling via C–O Bond Activation . ACS Catalysis 6: 4438–4442. Available: http://dx.doi.org/10.1021/acscatal.6b00801.
Publisher:
American Chemical Society (ACS)
Journal:
ACS Catalysis
Issue Date:
13-Jun-2016
DOI:
10.1021/acscatal.6b00801
Type:
Article
ISSN:
2155-5435; 2155-5435
Sponsors:
L.G., H.Y., and X.L. gratefully acknowledge the China Scholarship Council. C.-C.H. gratefully acknowledges DAAD for fellowship.
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorGuo, Linen
dc.contributor.authorHsiao, Chien-Chien
dc.contributor.authorYue, Huifengen
dc.contributor.authorLiu, Xiangqianen
dc.contributor.authorRueping, Magnusen
dc.date.accessioned2016-11-03T13:22:32Z-
dc.date.available2016-11-03T13:22:32Z-
dc.date.issued2016-06-13en
dc.identifier.citationGuo L, Hsiao C-C, Yue H, Liu X, Rueping M (2016) Nickel-Catalyzed C sp2 –C sp3 Cross-Coupling via C–O Bond Activation . ACS Catalysis 6: 4438–4442. Available: http://dx.doi.org/10.1021/acscatal.6b00801.en
dc.identifier.issn2155-5435en
dc.identifier.issn2155-5435en
dc.identifier.doi10.1021/acscatal.6b00801en
dc.identifier.urihttp://hdl.handle.net/10754/621676-
dc.description.abstractA new and efficient nickel-catalyzed alkylation of CAr-O electrophiles with B-alkyl-9-BBNs is described. The transformation is characterized by its functional group tolerance and provides a practical and versatile access to various Csp2-Csp3 bonds through Csp2-O substitution, without the restriction of β-hydride elimination. Moreover, the advantage of the newly developed method was demonstrated in a selective and sequential C-O bond activation process. © 2016 American Chemical Society.en
dc.description.sponsorshipL.G., H.Y., and X.L. gratefully acknowledge the China Scholarship Council. C.-C.H. gratefully acknowledges DAAD for fellowship.en
dc.publisherAmerican Chemical Society (ACS)en
dc.subjectB-alkyl-9-BBNsen
dc.titleNickel-Catalyzed C sp2 –C sp3 Cross-Coupling via C–O Bond Activationen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalACS Catalysisen
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen, Germanyen
kaust.authorRueping, Magnusen
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