Self-Assembly of Single-Crystal Silver Microflakes on Reduced Graphene Oxide and their Use in Ultrasensitive Sensors

Handle URI:
http://hdl.handle.net/10754/621674
Title:
Self-Assembly of Single-Crystal Silver Microflakes on Reduced Graphene Oxide and their Use in Ultrasensitive Sensors
Authors:
Chen, Ye ( 0000-0002-6893-5094 ) ; Tao, Jing; Hammami, Mohamed Amen ( 0000-0002-6162-3629 ) ; Hoang, Phuong Mai; Khashab, Niveen M. ( 0000-0003-2728-0666 )
Abstract:
Compared to 1D structures, 2D structures have higher specific and active surface, which drastically improves electron transfer and extensibility along 2D plane. Herein, 2D-single crystal silver microflakes (AgMFs) are prepared for the first time in situ on reduced graphene oxide (RGO) by solvothermal synthesis with thickness around 100 nm and length around 10 μm. The oriented attachment mechanism is hypothesized to control the silver crystal growth and self-assembly of reduced silver units to form single-crystal AgMF structure on RGO sheets. Employing it as an electrode to fabricate reliable and extremely sensitive pressure sensors verifies the applicability of this novel 2D structure. Contrary to nanowires, 2D microflakes can intercalate better within the polymer matrix to provide an enhanced network for electron movement. The designed sensor can retain more than 4.7 MPa-1 after 10 000 cycles. The design proves functional for monitoring various actions such as wrist movement, squatting, walking, and delicate finger touch with high durability. A highly sensitive and flexible pressure sensor is fabricated based on the self-assembly of silver microflakes on reduced graphene oxide. This sensor exhibits an excellent pressure sensitivity as it can retain more than 4.7 MPa-1 after 10 000 cycles. This system is successfully used to monitor wrist movement, walking, and squatting and can be applied in touch screen panels, robotic systems, and prosthetics. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Smart Hybrid Materials (SHMs) lab
Citation:
Chen Y, Tao J, Hammami MA, Hoang P, Khashab NM (2016) Self-Assembly of Single-Crystal Silver Microflakes on Reduced Graphene Oxide and their Use in Ultrasensitive Sensors. Advanced Materials Interfaces 3: 1500658. Available: http://dx.doi.org/10.1002/admi.201500658.
Publisher:
Wiley-Blackwell
Journal:
Advanced Materials Interfaces
Issue Date:
19-Jan-2016
DOI:
10.1002/admi.201500658
Type:
Article
ISSN:
2196-7350
Sponsors:
Y.C. and J.T. contributed equally to this work. This work was supported by King Abdullah University of Science and Technology (KAUST) and Sabic Innovative Plastics. The authors are grateful to Dr. Jian Zhou and Isaac A.Ventura of the Department of Mechanical Engineering and Yang Liu from the Electronics Workshop for assisting in the pressure sensitivity tests.
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/admi.201500658/abstract
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Controlled Release and Delivery Laboratory

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Yeen
dc.contributor.authorTao, Jingen
dc.contributor.authorHammami, Mohamed Amenen
dc.contributor.authorHoang, Phuong Maien
dc.contributor.authorKhashab, Niveen M.en
dc.date.accessioned2016-11-03T13:22:29Z-
dc.date.available2016-11-03T13:22:29Z-
dc.date.issued2016-01-19en
dc.identifier.citationChen Y, Tao J, Hammami MA, Hoang P, Khashab NM (2016) Self-Assembly of Single-Crystal Silver Microflakes on Reduced Graphene Oxide and their Use in Ultrasensitive Sensors. Advanced Materials Interfaces 3: 1500658. Available: http://dx.doi.org/10.1002/admi.201500658.en
dc.identifier.issn2196-7350en
dc.identifier.doi10.1002/admi.201500658en
dc.identifier.urihttp://hdl.handle.net/10754/621674-
dc.description.abstractCompared to 1D structures, 2D structures have higher specific and active surface, which drastically improves electron transfer and extensibility along 2D plane. Herein, 2D-single crystal silver microflakes (AgMFs) are prepared for the first time in situ on reduced graphene oxide (RGO) by solvothermal synthesis with thickness around 100 nm and length around 10 μm. The oriented attachment mechanism is hypothesized to control the silver crystal growth and self-assembly of reduced silver units to form single-crystal AgMF structure on RGO sheets. Employing it as an electrode to fabricate reliable and extremely sensitive pressure sensors verifies the applicability of this novel 2D structure. Contrary to nanowires, 2D microflakes can intercalate better within the polymer matrix to provide an enhanced network for electron movement. The designed sensor can retain more than 4.7 MPa-1 after 10 000 cycles. The design proves functional for monitoring various actions such as wrist movement, squatting, walking, and delicate finger touch with high durability. A highly sensitive and flexible pressure sensor is fabricated based on the self-assembly of silver microflakes on reduced graphene oxide. This sensor exhibits an excellent pressure sensitivity as it can retain more than 4.7 MPa-1 after 10 000 cycles. This system is successfully used to monitor wrist movement, walking, and squatting and can be applied in touch screen panels, robotic systems, and prosthetics. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.description.sponsorshipY.C. and J.T. contributed equally to this work. This work was supported by King Abdullah University of Science and Technology (KAUST) and Sabic Innovative Plastics. The authors are grateful to Dr. Jian Zhou and Isaac A.Ventura of the Department of Mechanical Engineering and Yang Liu from the Electronics Workshop for assisting in the pressure sensitivity tests.en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/admi.201500658/abstracten
dc.subjecthybrid membranesen
dc.subjectnanocompositesen
dc.subjectself-assemblyen
dc.subjectsensorsen
dc.subjectsilver nanoparticles (AgNPs)en
dc.titleSelf-Assembly of Single-Crystal Silver Microflakes on Reduced Graphene Oxide and their Use in Ultrasensitive Sensorsen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentSmart Hybrid Materials (SHMs) laben
dc.identifier.journalAdvanced Materials Interfacesen
kaust.authorChen, Yeen
kaust.authorTao, Jingen
kaust.authorHammami, Mohamed Amenen
kaust.authorHoang, Phuong Maien
kaust.authorKhashab, Niveen M.en
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.