Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

Handle URI:
http://hdl.handle.net/10754/621673
Title:
Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests
Authors:
Luo, Xiaolong; Cao, Yu; Wang, Tao; Li, Guanghua; Li, Jiangang; Yang, Yonggang; Xu, Zhongxuan; Zhang, Jian; Huo, Qisheng; Liu, Yunling; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
A novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3); Physical Sciences and Engineering (PSE) Division
Citation:
Luo X, Cao Y, Wang T, Li G, Li J, et al. (2016) Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests. Journal of the American Chemical Society 138: 786–789. Available: http://dx.doi.org/10.1021/jacs.5b12516.
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
Issue Date:
12-Jan-2016
DOI:
10.1021/jacs.5b12516
Type:
Article
ISSN:
0002-7863; 1520-5126
Sponsors:
The authors gratefully acknowledge the financial support of the Natural Science Foundation of China (nos. 21373095, 21371067, and 21171064).
Is Supplemented By:
Luo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410364: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblm2; DOI:10.5517/cc1jblm2; HANDLE:http://hdl.handle.net/10754/624444; Luo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410365: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jbln3; DOI:10.5517/cc1jbln3; HANDLE:http://hdl.handle.net/10754/624445; Luo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410366: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblp4; DOI:10.5517/cc1jblp4; HANDLE:http://hdl.handle.net/10754/624446
Additional Links:
http://pubs.acs.org/doi/abs/10.1021/jacs.5b12516
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorLuo, Xiaolongen
dc.contributor.authorCao, Yuen
dc.contributor.authorWang, Taoen
dc.contributor.authorLi, Guanghuaen
dc.contributor.authorLi, Jiangangen
dc.contributor.authorYang, Yonggangen
dc.contributor.authorXu, Zhongxuanen
dc.contributor.authorZhang, Jianen
dc.contributor.authorHuo, Qishengen
dc.contributor.authorLiu, Yunlingen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2016-11-03T13:22:27Z-
dc.date.available2016-11-03T13:22:27Z-
dc.date.issued2016-01-12en
dc.identifier.citationLuo X, Cao Y, Wang T, Li G, Li J, et al. (2016) Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests. Journal of the American Chemical Society 138: 786–789. Available: http://dx.doi.org/10.1021/jacs.5b12516.en
dc.identifier.issn0002-7863en
dc.identifier.issn1520-5126en
dc.identifier.doi10.1021/jacs.5b12516en
dc.identifier.urihttp://hdl.handle.net/10754/621673-
dc.description.abstractA novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.en
dc.description.sponsorshipThe authors gratefully acknowledge the financial support of the Natural Science Foundation of China (nos. 21373095, 21371067, and 21171064).en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/jacs.5b12516en
dc.titleHost–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guestsen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, Chinaen
dc.contributor.institutionJiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry Chemical Engineering and Materials Science, Soochow University, Suzhou, Chinaen
dc.contributor.institutionState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, Chinaen
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByLuo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410364: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblm2en
dc.relation.isSupplementedByDOI:10.5517/cc1jblm2en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624444en
dc.relation.isSupplementedByLuo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410365: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jbln3en
dc.relation.isSupplementedByDOI:10.5517/cc1jbln3en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624445en
dc.relation.isSupplementedByLuo, X., Cao, Y., Wang, T., Li, G., Li, J., Yang, Y., … Eddaoudi, M. (2016). CCDC 1410366: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1jblp4en
dc.relation.isSupplementedByDOI:10.5517/cc1jblp4en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624446en
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