Solvent-Controlled Assembly of ionic Metal-Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Properties

Handle URI:
http://hdl.handle.net/10754/617193
Title:
Solvent-Controlled Assembly of ionic Metal-Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Properties
Authors:
Zheng, Bing; Sun, Xiaodong; Li, Guanghua; Cairns, Amy J; Kravtsov, Victor; Huo, Qisheng; Liu, Yunling; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
Four Metal-Organic Frameworks (MOFs) based on Indium and tetracarboxylate ligand have been synthesized through regulation of the solvent conditions, the resulted compounds not only exhibited rich structural topologies (pts, soc and unique topologies), but also interesting charge reversal framework features. By regulating the solvent, different building units (indium monomer, trimer) have been generated in situ, and they are connected with the ligand to form ionic frameworks 1-4, respectively. Among the synthesized four ionic frameworks, compounds 3 and 4 could keep their crystallinity upon heating temperature up to 300oC after fully removal of solvent guest molecules, they also exhibit the charge reversal framework features (3 adopts an overall cationic framework, while 4 has an anionic framework). Both compounds 3 and 4 exhibit significant uptake capacity for CO2 and H2, besides that, compounds 3 and 4 also present excellent selective adsorption of CO2 over N2 and CH4.
KAUST Department:
Advanced Membranes and Porous Materials Center (AMPMC)
Citation:
Solvent-Controlled Assembly of ionic Metal-Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Properties 2016 Crystal Growth & Design
Publisher:
American Chemical Society (ACS)
Journal:
Crystal Growth & Design
Issue Date:
15-Jul-2016
DOI:
10.1021/acs.cgd.6b01031
Type:
Article
ISSN:
1528-7483; 1528-7505
Sponsors:
This work was supported by grants from the National Natural Science Foundation of China (Nos. 21371067 and 21373095) and the Open Project of Key Laboratory of Polyoxometalate Science of Ministry of Education (130026513).
Is Supplemented By:
Zheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860713: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwmyb; DOI:10.5517/ccdc.csd.ccxwmyb; HANDLE:http://hdl.handle.net/10754/624601; Zheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860714: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwmzc; DOI:10.5517/ccdc.csd.ccxwmzc; HANDLE:http://hdl.handle.net/10754/624602; Zheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860715: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwn0f; DOI:10.5517/ccdc.csd.ccxwn0f; HANDLE:http://hdl.handle.net/10754/624603; Zheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860716: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwn1g; DOI:10.5517/ccdc.csd.ccxwn1g; HANDLE:http://hdl.handle.net/10754/624604
Additional Links:
http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b01031
Appears in Collections:
Articles

Full metadata record

DC FieldValue Language
dc.contributor.authorZheng, Bingen
dc.contributor.authorSun, Xiaodongen
dc.contributor.authorLi, Guanghuaen
dc.contributor.authorCairns, Amy Jen
dc.contributor.authorKravtsov, Victoren
dc.contributor.authorHuo, Qishengen
dc.contributor.authorLiu, Yunlingen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2016-07-19T09:51:33Z-
dc.date.available2016-07-19T09:51:33Z-
dc.date.issued2016-07-15-
dc.identifier.citationSolvent-Controlled Assembly of ionic Metal-Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Properties 2016 Crystal Growth & Designen
dc.identifier.issn1528-7483-
dc.identifier.issn1528-7505-
dc.identifier.doi10.1021/acs.cgd.6b01031-
dc.identifier.urihttp://hdl.handle.net/10754/617193-
dc.description.abstractFour Metal-Organic Frameworks (MOFs) based on Indium and tetracarboxylate ligand have been synthesized through regulation of the solvent conditions, the resulted compounds not only exhibited rich structural topologies (pts, soc and unique topologies), but also interesting charge reversal framework features. By regulating the solvent, different building units (indium monomer, trimer) have been generated in situ, and they are connected with the ligand to form ionic frameworks 1-4, respectively. Among the synthesized four ionic frameworks, compounds 3 and 4 could keep their crystallinity upon heating temperature up to 300oC after fully removal of solvent guest molecules, they also exhibit the charge reversal framework features (3 adopts an overall cationic framework, while 4 has an anionic framework). Both compounds 3 and 4 exhibit significant uptake capacity for CO2 and H2, besides that, compounds 3 and 4 also present excellent selective adsorption of CO2 over N2 and CH4.en
dc.description.sponsorshipThis work was supported by grants from the National Natural Science Foundation of China (Nos. 21371067 and 21373095) and the Open Project of Key Laboratory of Polyoxometalate Science of Ministry of Education (130026513).en
dc.language.isoenen
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b01031en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Crystal Growth & Design, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b01031.en
dc.titleSolvent-Controlled Assembly of ionic Metal-Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Propertiesen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Center (AMPMC)en
dc.identifier.journalCrystal Growth & Designen
dc.eprint.versionPost-printen
dc.contributor.institutionState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. Chinaen
dc.contributor.institutionInstitute of Applied Physics of Academy of Sciences of Moldova, Academy str. 5, MD 2028 Chisinau, Moldovaen
dc.contributor.institutionKey Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, P. R. Chinaen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorCairns, Amy Jen
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByZheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860713: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwmyben
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.ccxwmyben
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624601en
dc.relation.isSupplementedByZheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860714: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwmzcen
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.ccxwmzcen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624602en
dc.relation.isSupplementedByZheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860715: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwn0fen
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.ccxwn0fen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624603en
dc.relation.isSupplementedByZheng, B., Sun, X., Li, G., Cairns, A. J., Kravtsov, V. C., Huo, Q., … Eddaoudi, M. (2016). CCDC 860716: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.ccxwn1gen
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.ccxwn1gen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624604en
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