Integrating Transition Metals into Nanomaterials: Strategies and Applications

Handle URI:
http://hdl.handle.net/10754/609540
Title:
Integrating Transition Metals into Nanomaterials: Strategies and Applications
Authors:
Fhayli, Karim ( 0000-0002-7631-4570 )
Abstract:
Transition metals complexes have been involved in various catalytic, biomedical and industrial applications, but only lately they have been associated with nanomaterials to produce innovative and well-defined new hybrid systems. The introduction of transition metals into nanomaterials is important to bear the advantages of metals to nanoscale and also to raise the stability of nanomaterials. In this dissertation, we study two approaches of associating transition metals into nanomaterials. The first approach is via spontaneous self-organization based assembly of small molecule amphiphiles and bulky hydrophilic polymers to produce organic-inorganic hybrid materials that have nanoscale features and can be precisely controlled depending on the experimental conditions used. These hybrid materials can successfully act as templates to design new porous material with interesting architecture. The second approach studied is via electroless reduction of transition metals on the surface of nanocarbons (nanotubes and nanodiamonds) without using any reducing agents or catalysts. The synthesis of these systems is highly efficient and facile resulting in stable and mechanically robust new materials with promising applications in catalysis.
Advisors:
Khashab, Niveen M. ( 0000-0003-2728-0666 )
Committee Member:
Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Hadjichristidis, Nikolaos ( 0000-0003-1442-1714 ) ; Hamdan, Samir; Almalik, Abdulaziz
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Program:
Chemical Sciences
Issue Date:
14-Apr-2016
Type:
Dissertation
Appears in Collections:
Dissertations; Physical Sciences and Engineering (PSE) Division; Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.advisorKhashab, Niveen M.en
dc.contributor.authorFhayli, Karimen
dc.date.accessioned2016-05-17T09:41:55Zen
dc.date.available2016-05-17T09:41:55Zen
dc.date.issued2016-04-14en
dc.identifier.urihttp://hdl.handle.net/10754/609540en
dc.description.abstractTransition metals complexes have been involved in various catalytic, biomedical and industrial applications, but only lately they have been associated with nanomaterials to produce innovative and well-defined new hybrid systems. The introduction of transition metals into nanomaterials is important to bear the advantages of metals to nanoscale and also to raise the stability of nanomaterials. In this dissertation, we study two approaches of associating transition metals into nanomaterials. The first approach is via spontaneous self-organization based assembly of small molecule amphiphiles and bulky hydrophilic polymers to produce organic-inorganic hybrid materials that have nanoscale features and can be precisely controlled depending on the experimental conditions used. These hybrid materials can successfully act as templates to design new porous material with interesting architecture. The second approach studied is via electroless reduction of transition metals on the surface of nanocarbons (nanotubes and nanodiamonds) without using any reducing agents or catalysts. The synthesis of these systems is highly efficient and facile resulting in stable and mechanically robust new materials with promising applications in catalysis.en
dc.language.isoenen
dc.subjectTransition Metalsen
dc.subjectNanomaterialsen
dc.subjectSelf-assemblyen
dc.subjectElectroless depositionen
dc.subjectDrug deliveryen
dc.subjectPlasmonicen
dc.titleIntegrating Transition Metals into Nanomaterials: Strategies and Applicationsen
dc.typeDissertationen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
thesis.degree.grantorKing Abdullah University of Science and Technologyen_GB
dc.contributor.committeememberHuang, Kuo-Weien
dc.contributor.committeememberHadjichristidis, Nikolaosen
dc.contributor.committeememberHamdan, Samiren
dc.contributor.committeememberAlmalik, Abdulazizen
thesis.degree.disciplineChemical Sciencesen
thesis.degree.nameDoctor of Philosophyen
dc.person.id122213en
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