Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

Handle URI:
http://hdl.handle.net/10754/608587
Title:
Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity
Authors:
Huang, Wei; Wang, Zi Jun; Ma, Beatriz Chiyin; Ghasimi, Saman; Gehrig, Dominik; Laquai, Frederic ( 0000-0002-5887-6158 ) ; Landfester, Katharina; Zhang, Kai A. I.
Abstract:
Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.
KAUST Department:
Material Science and Engineering Department
Citation:
Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity 2016 J. Mater. Chem. A
Publisher:
Royal Society of Chemistry (RSC)
Journal:
J. Mater. Chem. A
Issue Date:
11-Apr-2016
DOI:
10.1039/C6TA01828A
Type:
Article
ISSN:
2050-7488; 2050-7496
Sponsors:
The authors thank the Max Planck Society for the financial support. W. H. thanks the China Scholarship Council (CSC) (No. 201406240010) for the scholarship. Z. J. W. thanks the fellowship by the Excellence Initiative (DFG/GSC 266) of the graduate school of excellence “MAINZ” (Materials Science in Mainz). B. C. M. acknowledges the financial support from DAAD, CAPES and CNPq. D. G thanks the Fonds der Chemischen Industrie (FCI) for the Kekule scholarship.
Additional Links:
http://xlink.rsc.org/?DOI=C6TA01828A
Appears in Collections:
Articles

Full metadata record

DC FieldValue Language
dc.contributor.authorHuang, Weien
dc.contributor.authorWang, Zi Junen
dc.contributor.authorMa, Beatriz Chiyinen
dc.contributor.authorGhasimi, Samanen
dc.contributor.authorGehrig, Dominiken
dc.contributor.authorLaquai, Fredericen
dc.contributor.authorLandfester, Katharinaen
dc.contributor.authorZhang, Kai A. I.en
dc.date.accessioned2016-05-08T14:50:24Zen
dc.date.available2016-05-08T14:50:24Zen
dc.date.issued2016-04-11en
dc.identifier.citationHollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity 2016 J. Mater. Chem. Aen
dc.identifier.issn2050-7488en
dc.identifier.issn2050-7496en
dc.identifier.doi10.1039/C6TA01828Aen
dc.identifier.urihttp://hdl.handle.net/10754/608587en
dc.description.abstractHerein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.en
dc.description.sponsorshipThe authors thank the Max Planck Society for the financial support. W. H. thanks the China Scholarship Council (CSC) (No. 201406240010) for the scholarship. Z. J. W. thanks the fellowship by the Excellence Initiative (DFG/GSC 266) of the graduate school of excellence “MAINZ” (Materials Science in Mainz). B. C. M. acknowledges the financial support from DAAD, CAPES and CNPq. D. G thanks the Fonds der Chemischen Industrie (FCI) for the Kekule scholarship.en
dc.language.isoenen
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://xlink.rsc.org/?DOI=C6TA01828Aen
dc.rightsArchived with thanks to J. Mater. Chem. A. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. http://creativecommons.org/licenses/by/3.0/en
dc.titleHollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivityen
dc.typeArticleen
dc.contributor.departmentMaterial Science and Engineering Departmenten
dc.identifier.journalJ. Mater. Chem. Aen
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionMax Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germanyen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorLaquai, Fredericen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.