CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides

Handle URI:
http://hdl.handle.net/10754/604374
Title:
CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides
Authors:
Alkordi, Mohamed Helmi; Weseliński, Łukasz J; D´Elia, Valerio; Barman, Samir; Cadiau, Amandine; Hedhili, Mohamed N.; Cairns, Amy; Abdul Halim, Racha Ghassan; Basset, Jean-Marie ( 0000-0003-3166-8882 ) ; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
Novel porous organic polymers (POPs) have been synthesized using functionalized Cr and Co-salen complexes as molecular building blocks. The integration of metalosalen catalysts into the porous polymers backbone permits the successful utilization of the materials as solid-state catalysts for CO2-epoxide cycloadditions reactions with excellent catalytic performance under mild conditions of temperature and pressure. The catalyst proved to be fully recyclable and robust thus showing the potential of POPs as smart functional materials for the heterogenization of key catalytic elements.
KAUST Department:
Functional Materials Design, Discovery and Development (FMD3); Advanced Membranes and Porous Materials Center (AMPMC); Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC); Imaging and Characterization Core Lab
Citation:
CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides 2016 J. Mater. Chem. A
Publisher:
Royal Society of Chemistry (RSC)
Journal:
J. Mater. Chem. A
Issue Date:
30-Mar-2016
DOI:
10.1039/C5TA09321J
Type:
Article
ISSN:
2050-7488; 2050-7496
Sponsors:
Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2016/TA/C5TA09321J
Appears in Collections:
Articles; Advanced Nanofabrication, Imaging and Characterization Core Lab; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorAlkordi, Mohamed Helmien
dc.contributor.authorWeseliński, Łukasz Jen
dc.contributor.authorD´Elia, Valerioen
dc.contributor.authorBarman, Samiren
dc.contributor.authorCadiau, Amandineen
dc.contributor.authorHedhili, Mohamed N.en
dc.contributor.authorCairns, Amyen
dc.contributor.authorAbdul Halim, Racha Ghassanen
dc.contributor.authorBasset, Jean-Marieen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2016-04-04T13:13:51Zen
dc.date.available2016-04-04T13:13:51Zen
dc.date.issued2016-03-30en
dc.identifier.citationCO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides 2016 J. Mater. Chem. Aen
dc.identifier.issn2050-7488en
dc.identifier.issn2050-7496en
dc.identifier.doi10.1039/C5TA09321Jen
dc.identifier.urihttp://hdl.handle.net/10754/604374en
dc.description.abstractNovel porous organic polymers (POPs) have been synthesized using functionalized Cr and Co-salen complexes as molecular building blocks. The integration of metalosalen catalysts into the porous polymers backbone permits the successful utilization of the materials as solid-state catalysts for CO2-epoxide cycloadditions reactions with excellent catalytic performance under mild conditions of temperature and pressure. The catalyst proved to be fully recyclable and robust thus showing the potential of POPs as smart functional materials for the heterogenization of key catalytic elements.en
dc.description.sponsorshipResearch reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).en
dc.language.isoenen
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2016/TA/C5TA09321Jen
dc.rightsArchived with thanks to J. Mater. Chem. Aen
dc.titleCO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxidesen
dc.typeArticleen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentAdvanced Membranes and Porous Materials Center (AMPMC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentImaging and Characterization Core Laben
dc.identifier.journalJ. Mater. Chem. Aen
dc.eprint.versionPost-printen
dc.contributor.institutionDepartment of Materials Science and Engineering, Vidyasirimedhi Institute of Science and Technology, 21210, WangChan, Rayong, Thailanden
dc.contributor.institutionZewail City of Science and Technology, Center for Materials Science, Sheikh Zayed Dist., 6 th of October, 12588, Giza, Egypten
dc.contributor.institutionDepartment of Chemistry, Michigan Technological University, 1400 Townsend Drive, Houghton, Michigan 49931, United Statesen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorEddaoudi, Mohameden
kaust.authorAlkordi, Mohamed Helmien
kaust.authorWeseliński, Łukasz Jen
kaust.authorD´Elia, Valerioen
kaust.authorBarman, Samiren
kaust.authorCadiau, Amandineen
kaust.authorHedhili, Mohamed N.en
kaust.authorCairns, Amyen
kaust.authorAbdul Halim, Racha Ghassanen
kaust.authorBasset, Jean-Marieen
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