Unconventional Face-On Texture and Exceptional In-Plane Order of a High Mobility n-Type Polymer

Handle URI:
http://hdl.handle.net/10754/600127
Title:
Unconventional Face-On Texture and Exceptional In-Plane Order of a High Mobility n-Type Polymer
Authors:
Rivnay, Jonathan; Toney, Michael F.; Zheng, Yan; Kauvar, Isaac V.; Chen, Zhihua; Wagner, Veit; Facchetti, Antonio; Salleo, Alberto
Abstract:
Substantial in-plane crystallinity and dominant face-on stacking are observed in thin films of a high-mobility n-type rylene-thiophene copolymer. Spun films of the polymer, previously thought to have little or no order are found to exhibit an ordered microstructure at both interfaces, and in the bulk. The implications of this type of packing and crystalline morphology are discussed as they relate to thin-film transistors. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Citation:
Rivnay J, Toney MF, Zheng Y, Kauvar IV, Chen Z, et al. (2010) Unconventional Face-On Texture and Exceptional In-Plane Order of a High Mobility n-Type Polymer. Advanced Materials 22: 4359–4363. Available: http://dx.doi.org/10.1002/adma.201001202.
Publisher:
Wiley-Blackwell
Journal:
Advanced Materials
KAUST Grant Number:
KUS-C1-015-21
Issue Date:
9-Jul-2010
DOI:
10.1002/adma.201001202
PubMed ID:
20623753
Type:
Article
ISSN:
0935-9648
Sponsors:
Portions of this research were carried out at the Stanford Synchrotron Radiation Lightsource, a national user facility operated by Stanford University on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences. A.S. and J.R. gratefully acknowledge financial support from the National Science Foundation in the form of, respectively, a Career Award and a Graduate Student Fellowship. This publication was partially based on work supported by the Center for Advanced Molecular Photovoltaics (Award No KUS-C1-015-21), made by King Abdullah University of Science and Technology (KAUST).
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorRivnay, Jonathanen
dc.contributor.authorToney, Michael F.en
dc.contributor.authorZheng, Yanen
dc.contributor.authorKauvar, Isaac V.en
dc.contributor.authorChen, Zhihuaen
dc.contributor.authorWagner, Veiten
dc.contributor.authorFacchetti, Antonioen
dc.contributor.authorSalleo, Albertoen
dc.date.accessioned2016-02-28T06:43:15Zen
dc.date.available2016-02-28T06:43:15Zen
dc.date.issued2010-07-09en
dc.identifier.citationRivnay J, Toney MF, Zheng Y, Kauvar IV, Chen Z, et al. (2010) Unconventional Face-On Texture and Exceptional In-Plane Order of a High Mobility n-Type Polymer. Advanced Materials 22: 4359–4363. Available: http://dx.doi.org/10.1002/adma.201001202.en
dc.identifier.issn0935-9648en
dc.identifier.pmid20623753en
dc.identifier.doi10.1002/adma.201001202en
dc.identifier.urihttp://hdl.handle.net/10754/600127en
dc.description.abstractSubstantial in-plane crystallinity and dominant face-on stacking are observed in thin films of a high-mobility n-type rylene-thiophene copolymer. Spun films of the polymer, previously thought to have little or no order are found to exhibit an ordered microstructure at both interfaces, and in the bulk. The implications of this type of packing and crystalline morphology are discussed as they relate to thin-film transistors. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.description.sponsorshipPortions of this research were carried out at the Stanford Synchrotron Radiation Lightsource, a national user facility operated by Stanford University on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences. A.S. and J.R. gratefully acknowledge financial support from the National Science Foundation in the form of, respectively, a Career Award and a Graduate Student Fellowship. This publication was partially based on work supported by the Center for Advanced Molecular Photovoltaics (Award No KUS-C1-015-21), made by King Abdullah University of Science and Technology (KAUST).en
dc.publisherWiley-Blackwellen
dc.subjectConducting polymersen
dc.subjectOrganic Field-Effect Transistorsen
dc.subjectStructure-Property Relationshipsen
dc.titleUnconventional Face-On Texture and Exceptional In-Plane Order of a High Mobility n-Type Polymeren
dc.typeArticleen
dc.identifier.journalAdvanced Materialsen
dc.contributor.institutionStanford University, Palo Alto, United Statesen
dc.contributor.institutionStanford Synchrotron Radiation Laboratory, Menlo Park, United Statesen
dc.contributor.institutionJacobs University Bremen, Bremen, Germanyen
dc.contributor.institutionPolyera Corporation, Skokie, United Statesen
kaust.grant.numberKUS-C1-015-21en
kaust.grant.fundedcenterCenter for Advanced Molecular Photovoltaics (CAMP)en

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