Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide

Handle URI:
http://hdl.handle.net/10754/600060
Title:
Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide
Authors:
Lee, S. Y. Tina; Cokoja, Mirza; Drees, Markus; Li, Yang; Mink, János; Herrmann, Wolfgang A.; Kühn, Fritz E.
Abstract:
Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Citation:
Lee SYT, Cokoja M, Drees M, Li Y, Mink J, et al. (2011) Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide. ChemSusChem 4: 1275–1279. Available: http://dx.doi.org/10.1002/cssc.201000445.
Publisher:
Wiley-Blackwell
Journal:
ChemSusChem
KAUST Grant Number:
KSA-C0069/UK-C0020
Issue Date:
26-Aug-2011
DOI:
10.1002/cssc.201000445
PubMed ID:
21922679
Type:
Article
ISSN:
1864-5631
Sponsors:
This publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time.
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorLee, S. Y. Tinaen
dc.contributor.authorCokoja, Mirzaen
dc.contributor.authorDrees, Markusen
dc.contributor.authorLi, Yangen
dc.contributor.authorMink, Jánosen
dc.contributor.authorHerrmann, Wolfgang A.en
dc.contributor.authorKühn, Fritz E.en
dc.date.accessioned2016-02-28T06:35:16Zen
dc.date.available2016-02-28T06:35:16Zen
dc.date.issued2011-08-26en
dc.identifier.citationLee SYT, Cokoja M, Drees M, Li Y, Mink J, et al. (2011) Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide. ChemSusChem 4: 1275–1279. Available: http://dx.doi.org/10.1002/cssc.201000445.en
dc.identifier.issn1864-5631en
dc.identifier.pmid21922679en
dc.identifier.doi10.1002/cssc.201000445en
dc.identifier.urihttp://hdl.handle.net/10754/600060en
dc.description.abstractMu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.description.sponsorshipThis publication is based on work supported by Award KSA-C0069/UK-C0020, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Dr. Bettina Bechlars for the measurement and refinement of the X-ray single crystal structure of complex 1. The authors also thank the Leibniz-Rechenzentrum for providing computing time.en
dc.publisherWiley-Blackwellen
dc.subjectacrylic aciden
dc.subjectcarbon dioxide fixationen
dc.subjecthomogeneous catalysisen
dc.subjectligand effectsen
dc.subjectnickelen
dc.titleTransformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxideen
dc.typeArticleen
dc.identifier.journalChemSusChemen
dc.contributor.institutionTechnische Universitat Munchen, Munich, Germanyen
dc.contributor.institutionPannon Egyetem, Veszprem, Hungaryen
kaust.grant.numberKSA-C0069/UK-C0020en

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