Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2

Handle URI:
http://hdl.handle.net/10754/599831
Title:
Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2
Authors:
Zhu, Guowei; Ni, Lei; Qi, Wei; Ding, Shuang; Li, Xiaoxin; Wang, Runwei; Qiu, Shilun
Abstract:
A new method to synthesis TS-1 has been developed using the carbon dioxide (CO2) as an alkalinity regulator that resulted in the increased framework Ti contents. The prepared catalyst had a Si/Ti ratio as low as 40 in contrast to the ratio of 56 prepared through conventional synthesis. The twin crystals with the length of 2 μm were formed via introduction of CO 2. The catalytic activity of TS-1 is remarkably enhanced compared with the conventional synthesis. © 2013 Elsevier B.V.
Citation:
Zhu G, Ni L, Qi W, Ding S, Li X, et al. (2014) Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2. Inorganic Chemistry Communications 40: 129–132. Available: http://dx.doi.org/10.1016/j.inoche.2013.11.026.
Publisher:
Elsevier BV
Journal:
Inorganic Chemistry Communications
KAUST Grant Number:
CRG-1-2012-LAI-009
Issue Date:
Feb-2014
DOI:
10.1016/j.inoche.2013.11.026
Type:
Article
ISSN:
1387-7003
Sponsors:
This work was supported by the National Basic Research Program of China (2011CB808703, 2012CB821700), "111" project (B07016) and Award Project of KAUST (CRG-1-2012-LAI-009).
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorZhu, Guoweien
dc.contributor.authorNi, Leien
dc.contributor.authorQi, Weien
dc.contributor.authorDing, Shuangen
dc.contributor.authorLi, Xiaoxinen
dc.contributor.authorWang, Runweien
dc.contributor.authorQiu, Shilunen
dc.date.accessioned2016-02-28T06:10:51Zen
dc.date.available2016-02-28T06:10:51Zen
dc.date.issued2014-02en
dc.identifier.citationZhu G, Ni L, Qi W, Ding S, Li X, et al. (2014) Synthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2. Inorganic Chemistry Communications 40: 129–132. Available: http://dx.doi.org/10.1016/j.inoche.2013.11.026.en
dc.identifier.issn1387-7003en
dc.identifier.doi10.1016/j.inoche.2013.11.026en
dc.identifier.urihttp://hdl.handle.net/10754/599831en
dc.description.abstractA new method to synthesis TS-1 has been developed using the carbon dioxide (CO2) as an alkalinity regulator that resulted in the increased framework Ti contents. The prepared catalyst had a Si/Ti ratio as low as 40 in contrast to the ratio of 56 prepared through conventional synthesis. The twin crystals with the length of 2 μm were formed via introduction of CO 2. The catalytic activity of TS-1 is remarkably enhanced compared with the conventional synthesis. © 2013 Elsevier B.V.en
dc.description.sponsorshipThis work was supported by the National Basic Research Program of China (2011CB808703, 2012CB821700), "111" project (B07016) and Award Project of KAUST (CRG-1-2012-LAI-009).en
dc.publisherElsevier BVen
dc.subjectAlkalinity regulatoren
dc.subjectCrystal morphologyen
dc.subjectFramework Ti contenten
dc.titleSynthesis and morphology research of framework Ti-rich TS-1 containing no extraframework Ti species in the presence of CO2en
dc.typeArticleen
dc.identifier.journalInorganic Chemistry Communicationsen
dc.contributor.institutionBeihua University, Jilin, Chinaen
dc.contributor.institutionJilin University, Changchun, Chinaen
dc.contributor.institutionOil Refinery of Jilin Petrochemical Company, Jilin, Chinaen
kaust.grant.numberCRG-1-2012-LAI-009en
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