Symmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyads

Handle URI:
http://hdl.handle.net/10754/599826
Title:
Symmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyads
Authors:
Whited, Matthew T.; Patel, Niral M.; Roberts, Sean T.; Allen, Kathryn; Djurovich, Peter I.; Bradforth, Stephen E.; Thompson, Mark E.
Abstract:
We report the synthesis and characterization of symmetric BODIPY dyads where the chromophores are attached at the meso position, using either a phenylene bridge or direct linkage. Both molecules undergo symmetry-breaking intramolecular charge transfer in the excited state, and the directly linked dyad serves as a visible-light-absorbing analogue of 9,9′-bianthryl.
Citation:
Whited MT, Patel NM, Roberts ST, Allen K, Djurovich PI, et al. (2012) Symmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyads. Chem Commun 48: 284–286. Available: http://dx.doi.org/10.1039/c1cc12260f.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
KAUST Grant Number:
KUS-C1-015-21
Issue Date:
2012
DOI:
10.1039/c1cc12260f
PubMed ID:
22105418
Type:
Article
ISSN:
1359-7345; 1364-548X
Sponsors:
We acknowledge financial support from the Center for Advanced Molecular Photovoltaics (CAMP) (KUS-C1-015-21) of the King Abdullah University of Science and Technology and Global Photonic Corporation. Femtosecond transient absorption measurements were performed with support from the Department of Energy's Energy Frontier Research Center program (Award: DE-SC0001011). STR acknowledges an ACC-F fellowship from the National Science Foundation (CHE-0937015).
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorWhited, Matthew T.en
dc.contributor.authorPatel, Niral M.en
dc.contributor.authorRoberts, Sean T.en
dc.contributor.authorAllen, Kathrynen
dc.contributor.authorDjurovich, Peter I.en
dc.contributor.authorBradforth, Stephen E.en
dc.contributor.authorThompson, Mark E.en
dc.date.accessioned2016-02-28T06:10:44Zen
dc.date.available2016-02-28T06:10:44Zen
dc.date.issued2012en
dc.identifier.citationWhited MT, Patel NM, Roberts ST, Allen K, Djurovich PI, et al. (2012) Symmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyads. Chem Commun 48: 284–286. Available: http://dx.doi.org/10.1039/c1cc12260f.en
dc.identifier.issn1359-7345en
dc.identifier.issn1364-548Xen
dc.identifier.pmid22105418en
dc.identifier.doi10.1039/c1cc12260fen
dc.identifier.urihttp://hdl.handle.net/10754/599826en
dc.description.abstractWe report the synthesis and characterization of symmetric BODIPY dyads where the chromophores are attached at the meso position, using either a phenylene bridge or direct linkage. Both molecules undergo symmetry-breaking intramolecular charge transfer in the excited state, and the directly linked dyad serves as a visible-light-absorbing analogue of 9,9′-bianthryl.en
dc.description.sponsorshipWe acknowledge financial support from the Center for Advanced Molecular Photovoltaics (CAMP) (KUS-C1-015-21) of the King Abdullah University of Science and Technology and Global Photonic Corporation. Femtosecond transient absorption measurements were performed with support from the Department of Energy's Energy Frontier Research Center program (Award: DE-SC0001011). STR acknowledges an ACC-F fellowship from the National Science Foundation (CHE-0937015).en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleSymmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyadsen
dc.typeArticleen
dc.identifier.journalChem. Commun.en
dc.contributor.institutionUniversity of Southern California, Los Angeles, United Statesen
kaust.grant.numberKUS-C1-015-21en
kaust.grant.fundedcenterCenter for Advanced Molecular Photovoltaics (CAMP)en

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