Rolling Up the Sheet: Constructing Metal–Organic Lamellae and Nanotubes from a [{Mn 3 (propanediolato) 2 }(dicyanamide) 2 ] n Honeycomb Skeleton

Handle URI:
http://hdl.handle.net/10754/599537
Title:
Rolling Up the Sheet: Constructing Metal–Organic Lamellae and Nanotubes from a [{Mn 3 (propanediolato) 2 }(dicyanamide) 2 ] n Honeycomb Skeleton
Authors:
Wu, Gang; Bai, Jiaquan; Jiang, Yuan; Li, Guanghua; Huang, Jian; Li, Yi; Anson, Christopher E.; Powell, Annie K.; Qiu, Shilun
Abstract:
Target synthesis of metal-organic nanotubes (MONTs) through a classic "rolling-up" mechanism remains a big challenge for coordination chemists. In this work, we report three 2D lamellar compounds and one (4,0) zigzag MONT based on a common honeycomb coordination skeleton. Our synthetic strategy toward sheet/tube superstructure transformation is to asymmetrically modify the inter-layer interactions by gradually increasing the size of the amine templates. Eventually, to relieve the surface tension of individual layers and to enhance surface areas and optimize host-guest interactions to accommodate bigger guests, spontaneous rolling up to form a tubular structure was achieved. © 2013 American Chemical Society.
Citation:
Wu G, Bai J, Jiang Y, Li G, Huang J, et al. (2013) Rolling Up the Sheet: Constructing Metal–Organic Lamellae and Nanotubes from a [{Mn 3 (propanediolato) 2 }(dicyanamide) 2 ] n Honeycomb Skeleton . Journal of the American Chemical Society 135: 18276–18279. Available: http://dx.doi.org/10.1021/ja409569q.
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
KAUST Grant Number:
CRG-1-2012-LAI-009
Issue Date:
11-Dec-2013
DOI:
10.1021/ja409569q
PubMed ID:
24261593
Type:
Article
ISSN:
0002-7863; 1520-5126
Sponsors:
Dedicated to the memory of Ian J. Hewitt. This work was supported by the National Basic Research Program of China (2011CB808703, 2012CB821700), National Natural Science Foundation of China (Grant nos. 20901027, 91022030, 21261130584), "111" project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).
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Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorWu, Gangen
dc.contributor.authorBai, Jiaquanen
dc.contributor.authorJiang, Yuanen
dc.contributor.authorLi, Guanghuaen
dc.contributor.authorHuang, Jianen
dc.contributor.authorLi, Yien
dc.contributor.authorAnson, Christopher E.en
dc.contributor.authorPowell, Annie K.en
dc.contributor.authorQiu, Shilunen
dc.date.accessioned2016-02-28T05:52:59Zen
dc.date.available2016-02-28T05:52:59Zen
dc.date.issued2013-12-11en
dc.identifier.citationWu G, Bai J, Jiang Y, Li G, Huang J, et al. (2013) Rolling Up the Sheet: Constructing Metal–Organic Lamellae and Nanotubes from a [{Mn 3 (propanediolato) 2 }(dicyanamide) 2 ] n Honeycomb Skeleton . Journal of the American Chemical Society 135: 18276–18279. Available: http://dx.doi.org/10.1021/ja409569q.en
dc.identifier.issn0002-7863en
dc.identifier.issn1520-5126en
dc.identifier.pmid24261593en
dc.identifier.doi10.1021/ja409569qen
dc.identifier.urihttp://hdl.handle.net/10754/599537en
dc.description.abstractTarget synthesis of metal-organic nanotubes (MONTs) through a classic "rolling-up" mechanism remains a big challenge for coordination chemists. In this work, we report three 2D lamellar compounds and one (4,0) zigzag MONT based on a common honeycomb coordination skeleton. Our synthetic strategy toward sheet/tube superstructure transformation is to asymmetrically modify the inter-layer interactions by gradually increasing the size of the amine templates. Eventually, to relieve the surface tension of individual layers and to enhance surface areas and optimize host-guest interactions to accommodate bigger guests, spontaneous rolling up to form a tubular structure was achieved. © 2013 American Chemical Society.en
dc.description.sponsorshipDedicated to the memory of Ian J. Hewitt. This work was supported by the National Basic Research Program of China (2011CB808703, 2012CB821700), National Natural Science Foundation of China (Grant nos. 20901027, 91022030, 21261130584), "111" project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleRolling Up the Sheet: Constructing Metal–Organic Lamellae and Nanotubes from a [{Mn 3 (propanediolato) 2 }(dicyanamide) 2 ] n Honeycomb Skeletonen
dc.typeArticleen
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionJilin University, Changchun, Chinaen
dc.contributor.institutionKarlsruhe Institute of Technology, Campus South, Karlsruhe, Germanyen
dc.contributor.institutionKarlsruhe Institute of Technology, Campus North, Eggenstein-Leopoldshafen, Germanyen
kaust.grant.numberCRG-1-2012-LAI-009en

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