Particle-scale structure in frozen colloidal suspensions from small-angle x-ray scattering

Handle URI:
http://hdl.handle.net/10754/599145
Title:
Particle-scale structure in frozen colloidal suspensions from small-angle x-ray scattering
Authors:
Spannuth, Melissa; Mochrie, S. G. J.; Peppin, S. S. L.; Wettlaufer, J. S.
Abstract:
During directional solidification of the solvent in a colloidal suspension, the colloidal particles segregate from the growing solid, forming high-particle-density regions with structure on a hierarchy of length scales ranging from that of the particle-scale packing to the large-scale spacing between these regions. Previous work has concentrated mostly on the medium- to large-length scale structure, as it is the most accessible and thought to be more technologically relevant. However, the packing of the colloids at the particle scale is an important component not only in theoretical descriptions of the segregation process, but also to the utility of freeze-cast materials for new applications. Here we present the results of experiments in which we investigated this structure across a wide range of length scales using a combination of small-angle x-ray scattering and direct optical imaging. As expected, during freezing the particles were concentrated into regions between ice dendrites forming a microscopic pattern of high- and low-particle-density regions. X-ray scattering indicates that the particles in the high-density regions were so closely packed as to be touching. However, the arrangement of the particles does not conform to that predicted by standard interparticle pair potentials, suggesting that the particle packing induced by freezing differs from that formed during equilibrium densification processes. © 2011 American Physical Society.
Citation:
Spannuth M, Mochrie SGJ, Peppin SSL, Wettlaufer JS (2011) Particle-scale structure in frozen colloidal suspensions from small-angle x-ray scattering. Phys Rev E 83. Available: http://dx.doi.org/10.1103/PhysRevE.83.021402.
Publisher:
American Physical Society (APS)
Journal:
Physical Review E
KAUST Grant Number:
KUK-C1-013-04
Issue Date:
Feb-2011
DOI:
10.1103/PhysRevE.83.021402
PubMed ID:
21405844
Type:
Article
ISSN:
1539-3755; 1550-2376
Sponsors:
We thank S. Narayanan, A. Sandy, and M. Sprung for assistance with the SAXS experiments, and X. Lu, J. Neufeld, E. Thomson, and L. Wilen for useful discussions. M.S. was supported by the Graduate Research Fellowship Program of the National Science Foundation (NSF). S.G.J.M. thanks the NSF for support via Grant No. DMR-0906697. S.S.L.P. acknowledges support from the King Abdullah University of Science and Technology (KAUST), Award No. KUK-C1-013-04. J.S.W. acknowledges support from the NSF Grant No. OPP0440841 and the US Department of Energy (DoE) Grant No. DE-FG02-05ER15741. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the US DoE, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.
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Full metadata record

DC FieldValue Language
dc.contributor.authorSpannuth, Melissaen
dc.contributor.authorMochrie, S. G. J.en
dc.contributor.authorPeppin, S. S. L.en
dc.contributor.authorWettlaufer, J. S.en
dc.date.accessioned2016-02-25T13:53:42Zen
dc.date.available2016-02-25T13:53:42Zen
dc.date.issued2011-02en
dc.identifier.citationSpannuth M, Mochrie SGJ, Peppin SSL, Wettlaufer JS (2011) Particle-scale structure in frozen colloidal suspensions from small-angle x-ray scattering. Phys Rev E 83. Available: http://dx.doi.org/10.1103/PhysRevE.83.021402.en
dc.identifier.issn1539-3755en
dc.identifier.issn1550-2376en
dc.identifier.pmid21405844en
dc.identifier.doi10.1103/PhysRevE.83.021402en
dc.identifier.urihttp://hdl.handle.net/10754/599145en
dc.description.abstractDuring directional solidification of the solvent in a colloidal suspension, the colloidal particles segregate from the growing solid, forming high-particle-density regions with structure on a hierarchy of length scales ranging from that of the particle-scale packing to the large-scale spacing between these regions. Previous work has concentrated mostly on the medium- to large-length scale structure, as it is the most accessible and thought to be more technologically relevant. However, the packing of the colloids at the particle scale is an important component not only in theoretical descriptions of the segregation process, but also to the utility of freeze-cast materials for new applications. Here we present the results of experiments in which we investigated this structure across a wide range of length scales using a combination of small-angle x-ray scattering and direct optical imaging. As expected, during freezing the particles were concentrated into regions between ice dendrites forming a microscopic pattern of high- and low-particle-density regions. X-ray scattering indicates that the particles in the high-density regions were so closely packed as to be touching. However, the arrangement of the particles does not conform to that predicted by standard interparticle pair potentials, suggesting that the particle packing induced by freezing differs from that formed during equilibrium densification processes. © 2011 American Physical Society.en
dc.description.sponsorshipWe thank S. Narayanan, A. Sandy, and M. Sprung for assistance with the SAXS experiments, and X. Lu, J. Neufeld, E. Thomson, and L. Wilen for useful discussions. M.S. was supported by the Graduate Research Fellowship Program of the National Science Foundation (NSF). S.G.J.M. thanks the NSF for support via Grant No. DMR-0906697. S.S.L.P. acknowledges support from the King Abdullah University of Science and Technology (KAUST), Award No. KUK-C1-013-04. J.S.W. acknowledges support from the NSF Grant No. OPP0440841 and the US Department of Energy (DoE) Grant No. DE-FG02-05ER15741. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the US DoE, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.en
dc.publisherAmerican Physical Society (APS)en
dc.titleParticle-scale structure in frozen colloidal suspensions from small-angle x-ray scatteringen
dc.typeArticleen
dc.identifier.journalPhysical Review Een
dc.contributor.institutionYale University, New Haven, United Statesen
dc.contributor.institutionUniversity of Oxford, Oxford, United Kingdomen
dc.contributor.institutionUniversity of Houston, Houston, United Statesen
kaust.grant.numberKUK-C1-013-04en

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