N,N-Di aryl anilinosquaraines and Their Application to Organic Photovoltaics

Handle URI:
http://hdl.handle.net/10754/598927
Title:
N,N-Di aryl anilinosquaraines and Their Application to Organic Photovoltaics
Authors:
Wang, Siyi; Hall, Lincoln; Diev, Vyacheslav V.; Haiges, Ralf; Wei, Guodan; Xiao, Xin; Djurovich, Peter I.; Forrest, Stephen R.; Thompson, Mark E.
Abstract:
We report new derivatives of symmetric squaraine dyes with N,N-diarylanilino substituents that have high solubility and high absorptivity (ε = 0.71-4.1 ×105 M-1cm-1) in the red solar spectral region (λmax = 645-694 nm) making them promising candidates for application in organic photovoltaics (OPVs). Unsymmetrical N,N-diisobutylanilino- and N,N-diphenylanilino(diphenylamino) squaraines have also been prepared that give blue-shifted absorption spectra (λmax = 529-535 nm) relative to their symmetric counterparts. Compared to bis(N,N-diisobutylanilino)squaraine, both symmetrical and unsymmetrical N,N-diarylanilino squaraines show markedly broader absorption bands in solution than their N,N-dialkylanilino squaraine counterparts: the full width at half-maximum (fwhm) for N,N-diarylanilino squaraines range from 1280-1980 cm-1, while the fwhm value for the N,N-diisobutylanilino squarine is only 630 cm-1. The absorption bands for thin films of N,N-diarylanilino squaraines broaden further to 2500-3300 cm-1. N,N-Diarylanilino squaraines are fluorescent, albeit with lower quantum yields than bis(N,N-diisobutylanilino)squaraine (φPL = 0.02-0.66 and 0.80, respectively). OPVs were prepared with solution processed squaraine layers using the following structure: ITO/squaraine (66-85 Å)/C60 (400 Å)/BCP (100 Å)/Al (1000 Å), BCP = bathocuproine. Devices using thin films of the bis(N,N-diarylanilino)squaraines as donor layers show improved performance relative to OPVs prepared with bis(N,N-dialkylanilino) squaraines, i.e. bis(N,N-diisobutylanilino)squaraine: open-circuit voltage Voc = 0.59 ± 0.05 V, short-circuit current Jsc = 5.58 ± 0.16 mA/cm2, fill factor FF = 0.56 ± 0.03, and power conversion efficiency η = 1.8 ± 0.2% under 1 sun, AM1.5G simulated illumination, compared with bis(N,N-diphenylanilino)squaraine: V oc = 0.82 ± 0.02 V, Jsc = 6.71 ± 0.10 mA/cm2, FF = 0.59 ± 0.01, and η = 3.2 ± 0.1%. Morphological studies of thin films suggest that the solubility of bis(N,N-diarylanilino)squaraines plays an important role in controlling the optoelectronic properties of the OPVs. © 2011 American Chemical Society.
Citation:
Wang S, Hall L, Diev VV, Haiges R, Wei G, et al. (2011) N,N-Di aryl anilinosquaraines and Their Application to Organic Photovoltaics . Chem Mater 23: 4789–4798. Available: http://dx.doi.org/10.1021/cm2020803.
Publisher:
American Chemical Society (ACS)
Journal:
Chemistry of Materials
KAUST Grant Number:
KUS-C1-015-21
Issue Date:
8-Nov-2011
DOI:
10.1021/cm2020803
Type:
Article
ISSN:
0897-4756; 1520-5002
Sponsors:
Funding for this research was provided by the Center for Advanced Molecular Photovoltaics (CAMP) (award KUS-C1-015-21) of the King Abdullah University of Science and Technology (KAUST), the US Department of Energy Frontier Center at the University of Southern California (award DE-SC0001011, S.W. and M.E.T.), the US Department of Energy EERE Beyond the Horizon program (DE-FG36-08GO18022, G. W. and S.R.F.), and the Global Photonic Corporation. We also like to thank Dr. Frederico A. Rabuffetti for assistance with the TGA measurements.
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Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Siyien
dc.contributor.authorHall, Lincolnen
dc.contributor.authorDiev, Vyacheslav V.en
dc.contributor.authorHaiges, Ralfen
dc.contributor.authorWei, Guodanen
dc.contributor.authorXiao, Xinen
dc.contributor.authorDjurovich, Peter I.en
dc.contributor.authorForrest, Stephen R.en
dc.contributor.authorThompson, Mark E.en
dc.date.accessioned2016-02-25T13:43:52Zen
dc.date.available2016-02-25T13:43:52Zen
dc.date.issued2011-11-08en
dc.identifier.citationWang S, Hall L, Diev VV, Haiges R, Wei G, et al. (2011) N,N-Di aryl anilinosquaraines and Their Application to Organic Photovoltaics . Chem Mater 23: 4789–4798. Available: http://dx.doi.org/10.1021/cm2020803.en
dc.identifier.issn0897-4756en
dc.identifier.issn1520-5002en
dc.identifier.doi10.1021/cm2020803en
dc.identifier.urihttp://hdl.handle.net/10754/598927en
dc.description.abstractWe report new derivatives of symmetric squaraine dyes with N,N-diarylanilino substituents that have high solubility and high absorptivity (ε = 0.71-4.1 ×105 M-1cm-1) in the red solar spectral region (λmax = 645-694 nm) making them promising candidates for application in organic photovoltaics (OPVs). Unsymmetrical N,N-diisobutylanilino- and N,N-diphenylanilino(diphenylamino) squaraines have also been prepared that give blue-shifted absorption spectra (λmax = 529-535 nm) relative to their symmetric counterparts. Compared to bis(N,N-diisobutylanilino)squaraine, both symmetrical and unsymmetrical N,N-diarylanilino squaraines show markedly broader absorption bands in solution than their N,N-dialkylanilino squaraine counterparts: the full width at half-maximum (fwhm) for N,N-diarylanilino squaraines range from 1280-1980 cm-1, while the fwhm value for the N,N-diisobutylanilino squarine is only 630 cm-1. The absorption bands for thin films of N,N-diarylanilino squaraines broaden further to 2500-3300 cm-1. N,N-Diarylanilino squaraines are fluorescent, albeit with lower quantum yields than bis(N,N-diisobutylanilino)squaraine (φPL = 0.02-0.66 and 0.80, respectively). OPVs were prepared with solution processed squaraine layers using the following structure: ITO/squaraine (66-85 Å)/C60 (400 Å)/BCP (100 Å)/Al (1000 Å), BCP = bathocuproine. Devices using thin films of the bis(N,N-diarylanilino)squaraines as donor layers show improved performance relative to OPVs prepared with bis(N,N-dialkylanilino) squaraines, i.e. bis(N,N-diisobutylanilino)squaraine: open-circuit voltage Voc = 0.59 ± 0.05 V, short-circuit current Jsc = 5.58 ± 0.16 mA/cm2, fill factor FF = 0.56 ± 0.03, and power conversion efficiency η = 1.8 ± 0.2% under 1 sun, AM1.5G simulated illumination, compared with bis(N,N-diphenylanilino)squaraine: V oc = 0.82 ± 0.02 V, Jsc = 6.71 ± 0.10 mA/cm2, FF = 0.59 ± 0.01, and η = 3.2 ± 0.1%. Morphological studies of thin films suggest that the solubility of bis(N,N-diarylanilino)squaraines plays an important role in controlling the optoelectronic properties of the OPVs. © 2011 American Chemical Society.en
dc.description.sponsorshipFunding for this research was provided by the Center for Advanced Molecular Photovoltaics (CAMP) (award KUS-C1-015-21) of the King Abdullah University of Science and Technology (KAUST), the US Department of Energy Frontier Center at the University of Southern California (award DE-SC0001011, S.W. and M.E.T.), the US Department of Energy EERE Beyond the Horizon program (DE-FG36-08GO18022, G. W. and S.R.F.), and the Global Photonic Corporation. We also like to thank Dr. Frederico A. Rabuffetti for assistance with the TGA measurements.en
dc.publisherAmerican Chemical Society (ACS)en
dc.subjectorganic photovoltaicen
dc.subjectsolar cellen
dc.subjectSquaraine dyesen
dc.titleN,N-Di aryl anilinosquaraines and Their Application to Organic Photovoltaicsen
dc.typeArticleen
dc.identifier.journalChemistry of Materialsen
dc.contributor.institutionUniversity of Southern California, Los Angeles, United Statesen
dc.contributor.institutionUniversity Michigan Ann Arbor, Ann Arbor, United Statesen
kaust.grant.numberKUS-C1-015-21en
kaust.grant.fundedcenterCenter for Advanced Molecular Photovoltaics (CAMP)en
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