Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life

Handle URI:
http://hdl.handle.net/10754/598649
Title:
Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life
Authors:
Yao, Yan; McDowell, Matthew T.; Ryu, Ill; Wu, Hui; Liu, Nian; Hu, Liangbing; Nix, William D.; Cui, Yi
Abstract:
Silicon is a promising candidate for the anode material in lithium-ion batteries due to its high theoretical specific capacity. However, volume changes during cycling cause pulverization and capacity fade, and improving cycle life is a major research challenge. Here, we report a novel interconnected Si hollow nanosphere electrode that is capable of accommodating large volume changes without pulverization during cycling. We achieved the high initial discharge capacity of 2725 mAh g-1 with less than 8% capacity degradation every hundred cycles for 700 total cycles. Si hollow sphere electrodes also show a Coulombic efficiency of 99.5% in later cycles. Superior rate capability is demonstrated and attributed to fast lithium diffusion in the interconnected Si hollow structure. © 2011 American Chemical Society.
Citation:
Yao Y, McDowell MT, Ryu I, Wu H, Liu N, et al. (2011) Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life. Nano Lett 11: 2949–2954. Available: http://dx.doi.org/10.1021/nl201470j.
Publisher:
American Chemical Society (ACS)
Journal:
Nano Letters
KAUST Grant Number:
KUS-l1-001-12
Issue Date:
13-Jul-2011
DOI:
10.1021/nl201470j
PubMed ID:
21668030
Type:
Article
ISSN:
1530-6984; 1530-6992
Sponsors:
This work was partially supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231, Subcontract NO. 6951379 under the Batteries for Advanced Transportation Technologies (BATT) Program. This work is also partially supported by the Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering, under Contract DE-AC02-76SF0051, through the SLAC National Accelerator Laboratory LDRD project. Y.C. acknowledges support from the King Abdullah University of Science and Technology (KAUST) Investigator Award (No. KUS-l1-001-12). W.D.N and I.R. were supported by the Office of Science, Office of Basic Energy Sciences, of the US Department of Energy under Contract No. DE-FG02-04ER46163. M.T.M. gratefully acknowledges support from the Chevron Stanford Graduate Fellowship, the National Defense Science and Engineering Graduate Fellowship, and the National Science Foundation Graduate Fellowship.
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Full metadata record

DC FieldValue Language
dc.contributor.authorYao, Yanen
dc.contributor.authorMcDowell, Matthew T.en
dc.contributor.authorRyu, Illen
dc.contributor.authorWu, Huien
dc.contributor.authorLiu, Nianen
dc.contributor.authorHu, Liangbingen
dc.contributor.authorNix, William D.en
dc.contributor.authorCui, Yien
dc.date.accessioned2016-02-25T13:33:47Zen
dc.date.available2016-02-25T13:33:47Zen
dc.date.issued2011-07-13en
dc.identifier.citationYao Y, McDowell MT, Ryu I, Wu H, Liu N, et al. (2011) Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life. Nano Lett 11: 2949–2954. Available: http://dx.doi.org/10.1021/nl201470j.en
dc.identifier.issn1530-6984en
dc.identifier.issn1530-6992en
dc.identifier.pmid21668030en
dc.identifier.doi10.1021/nl201470jen
dc.identifier.urihttp://hdl.handle.net/10754/598649en
dc.description.abstractSilicon is a promising candidate for the anode material in lithium-ion batteries due to its high theoretical specific capacity. However, volume changes during cycling cause pulverization and capacity fade, and improving cycle life is a major research challenge. Here, we report a novel interconnected Si hollow nanosphere electrode that is capable of accommodating large volume changes without pulverization during cycling. We achieved the high initial discharge capacity of 2725 mAh g-1 with less than 8% capacity degradation every hundred cycles for 700 total cycles. Si hollow sphere electrodes also show a Coulombic efficiency of 99.5% in later cycles. Superior rate capability is demonstrated and attributed to fast lithium diffusion in the interconnected Si hollow structure. © 2011 American Chemical Society.en
dc.description.sponsorshipThis work was partially supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231, Subcontract NO. 6951379 under the Batteries for Advanced Transportation Technologies (BATT) Program. This work is also partially supported by the Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering, under Contract DE-AC02-76SF0051, through the SLAC National Accelerator Laboratory LDRD project. Y.C. acknowledges support from the King Abdullah University of Science and Technology (KAUST) Investigator Award (No. KUS-l1-001-12). W.D.N and I.R. were supported by the Office of Science, Office of Basic Energy Sciences, of the US Department of Energy under Contract No. DE-FG02-04ER46163. M.T.M. gratefully acknowledges support from the Chevron Stanford Graduate Fellowship, the National Defense Science and Engineering Graduate Fellowship, and the National Science Foundation Graduate Fellowship.en
dc.publisherAmerican Chemical Society (ACS)en
dc.subjectenergy storageen
dc.subjectlithium induced stressen
dc.subjectSilicon hollow sphere electrodeen
dc.subjectvolume expansionen
dc.titleInterconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Lifeen
dc.typeArticleen
dc.identifier.journalNano Lettersen
dc.contributor.institutionStanford University, Palo Alto, United Statesen
kaust.grant.numberKUS-l1-001-12en

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