Insights Into the Carbene-Initiated Aggregation of [Fe(cot)2]

Handle URI:
http://hdl.handle.net/10754/598631
Title:
Insights Into the Carbene-Initiated Aggregation of [Fe(cot)2]
Authors:
Lavallo, Vincent; El-Batta, Amer; Bertrand, Guy; Grubbs, Robert H.
Abstract:
Carbenes attack! Stable carbenes react with [Fe(cot)2] in very different ways. Whereas the classical N-heterocyclic carbenes induce the formation of tetra- and trimetallic iron clusters, abnormal NHCs and carbocyclic carbenes (BACs) form mono- and bimetallic iron complexes. Cyclic (alkyl)(amino)carbenes (CAACs) react with [Fe(cot)2] in a completely different manner, namely through outersphere [4+1] cycloaddition.
Citation:
Lavallo V, El-Batta A, Bertrand G, Grubbs RH (2010) Insights Into the Carbene-Initiated Aggregation of [Fe(cot)2]. Angew Chem 123: 282–285. Available: http://dx.doi.org/10.1002/ange.201005212.
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie
KAUST Grant Number:
K-C1-019-12
Issue Date:
25-Nov-2010
DOI:
10.1002/ange.201005212
Type:
Article
ISSN:
0044-8249
Sponsors:
We gratefully acknowledge financial support from the NIH (grants 5R01 GM 31332 and R01 GM 68825, and N.R.S.A. fellowship for V.L. This publication was based on work supported by Award No. K-C1-019-12 made by King Abdullah University of Science and Technology (KAUST). The support of King Fahd University of Petroleum and Minerals (KFUPM) is also highly appreciated. We thank L. M. Henling and M. W. Day (California Institute of Technology) for X-ray crystallographic analysis. The Bruker KAPPA APEX II X-ray diffractometer was purchased via an NSF Chemistry Research Instrumentation and Facilities: Multi-User award to the California Institute of Technology, CHE-0639094.
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorLavallo, Vincenten
dc.contributor.authorEl-Batta, Ameren
dc.contributor.authorBertrand, Guyen
dc.contributor.authorGrubbs, Robert H.en
dc.date.accessioned2016-02-25T13:33:28Zen
dc.date.available2016-02-25T13:33:28Zen
dc.date.issued2010-11-25en
dc.identifier.citationLavallo V, El-Batta A, Bertrand G, Grubbs RH (2010) Insights Into the Carbene-Initiated Aggregation of [Fe(cot)2]. Angew Chem 123: 282–285. Available: http://dx.doi.org/10.1002/ange.201005212.en
dc.identifier.issn0044-8249en
dc.identifier.doi10.1002/ange.201005212en
dc.identifier.urihttp://hdl.handle.net/10754/598631en
dc.description.abstractCarbenes attack! Stable carbenes react with [Fe(cot)2] in very different ways. Whereas the classical N-heterocyclic carbenes induce the formation of tetra- and trimetallic iron clusters, abnormal NHCs and carbocyclic carbenes (BACs) form mono- and bimetallic iron complexes. Cyclic (alkyl)(amino)carbenes (CAACs) react with [Fe(cot)2] in a completely different manner, namely through outersphere [4+1] cycloaddition.en
dc.description.sponsorshipWe gratefully acknowledge financial support from the NIH (grants 5R01 GM 31332 and R01 GM 68825, and N.R.S.A. fellowship for V.L. This publication was based on work supported by Award No. K-C1-019-12 made by King Abdullah University of Science and Technology (KAUST). The support of King Fahd University of Petroleum and Minerals (KFUPM) is also highly appreciated. We thank L. M. Henling and M. W. Day (California Institute of Technology) for X-ray crystallographic analysis. The Bruker KAPPA APEX II X-ray diffractometer was purchased via an NSF Chemistry Research Instrumentation and Facilities: Multi-User award to the California Institute of Technology, CHE-0639094.en
dc.publisherWiley-Blackwellen
dc.titleInsights Into the Carbene-Initiated Aggregation of [Fe(cot)2]en
dc.typeArticleen
dc.identifier.journalAngewandte Chemieen
dc.contributor.institutionDivision of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125 (USA)en
dc.contributor.institutionKing Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia)en
dc.contributor.institutionDepartment of Chemistry and KAUST Center in Development, King Fahd University of Petroleum and Mineralsen
dc.contributor.institutionUCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA)en
kaust.grant.numberK-C1-019-12en
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