Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layer

Handle URI:
http://hdl.handle.net/10754/598587
Title:
Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layer
Authors:
Guarnera, Simone; Abate, Antonio; Zhang, Wei; Foster, Jamie M.; Richardson, Giles; Petrozza, Annamaria; Snaith, Henry J.
Abstract:
© 2015 American Chemical Society. Hybrid perovskites represent a new paradigm for photovoltaics, which have the potential to overcome the performance limits of current technologies and achieve low cost and high versatility. However, an efficiency drop is often observed within the first few hundred hours of device operation, which could become an important issue. Here, we demonstrate that the electrode's metal migrating through the hole transporting material (HTM) layer and eventually contacting the perovskite is in part responsible for this early device degradation. We show that depositing the HTM within an insulating mesoporous "buffer layer" comprised of Al2O3 nanoparticles prevents the metal electrode migration while allowing for precise control of the HTM thickness. This enables an improvement in the solar cell fill factor and prevents degradation of the device after 350 h of operation. (Graph Presented).
Citation:
Guarnera S, Abate A, Zhang W, Foster JM, Richardson G, et al. (2015) Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layer . The Journal of Physical Chemistry Letters 6: 432–437. Available: http://dx.doi.org/10.1021/jz502703p.
Publisher:
American Chemical Society (ACS)
Journal:
The Journal of Physical Chemistry Letters
KAUST Grant Number:
KUK-C1-013-04
Issue Date:
5-Feb-2015
DOI:
10.1021/jz502703p
PubMed ID:
26261960
Type:
Article
ISSN:
1948-7185
Sponsors:
We thank the Engineering and Physical Sciences Research Council (EPSRC) APEX project for financial support and Dr. Ajay Ram Srimath Kandada and Ms. Stefanie Neutzner for useful discussions. J.M.F. and G.R. were part funded by the EPSRC through grant EP/I01702X/. This publication is partially based on work supported by award number KUK-C1-013-04, made by King Abdullah University of Science and Technology (KAUST), via an OCCAM visiting research fellowship awarded to G.R. The project was partially funded by the European Union Seventh Framework Programme [FP7/2007-2013] under grant agreement 316494 and grant agreement no. 604032 of the MESO project.
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorGuarnera, Simoneen
dc.contributor.authorAbate, Antonioen
dc.contributor.authorZhang, Weien
dc.contributor.authorFoster, Jamie M.en
dc.contributor.authorRichardson, Gilesen
dc.contributor.authorPetrozza, Annamariaen
dc.contributor.authorSnaith, Henry J.en
dc.date.accessioned2016-02-25T13:32:38Zen
dc.date.available2016-02-25T13:32:38Zen
dc.date.issued2015-02-05en
dc.identifier.citationGuarnera S, Abate A, Zhang W, Foster JM, Richardson G, et al. (2015) Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layer . The Journal of Physical Chemistry Letters 6: 432–437. Available: http://dx.doi.org/10.1021/jz502703p.en
dc.identifier.issn1948-7185en
dc.identifier.pmid26261960en
dc.identifier.doi10.1021/jz502703pen
dc.identifier.urihttp://hdl.handle.net/10754/598587en
dc.description.abstract© 2015 American Chemical Society. Hybrid perovskites represent a new paradigm for photovoltaics, which have the potential to overcome the performance limits of current technologies and achieve low cost and high versatility. However, an efficiency drop is often observed within the first few hundred hours of device operation, which could become an important issue. Here, we demonstrate that the electrode's metal migrating through the hole transporting material (HTM) layer and eventually contacting the perovskite is in part responsible for this early device degradation. We show that depositing the HTM within an insulating mesoporous "buffer layer" comprised of Al2O3 nanoparticles prevents the metal electrode migration while allowing for precise control of the HTM thickness. This enables an improvement in the solar cell fill factor and prevents degradation of the device after 350 h of operation. (Graph Presented).en
dc.description.sponsorshipWe thank the Engineering and Physical Sciences Research Council (EPSRC) APEX project for financial support and Dr. Ajay Ram Srimath Kandada and Ms. Stefanie Neutzner for useful discussions. J.M.F. and G.R. were part funded by the EPSRC through grant EP/I01702X/. This publication is partially based on work supported by award number KUK-C1-013-04, made by King Abdullah University of Science and Technology (KAUST), via an OCCAM visiting research fellowship awarded to G.R. The project was partially funded by the European Union Seventh Framework Programme [FP7/2007-2013] under grant agreement 316494 and grant agreement no. 604032 of the MESO project.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleImproving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layeren
dc.typeArticleen
dc.identifier.journalThe Journal of Physical Chemistry Lettersen
dc.contributor.institutionIstituto Italiano di Tecnologia, Genoa, Italyen
dc.contributor.institutionPolitecnico di Milano, Milan, Italyen
dc.contributor.institutionUniversity of Oxford, Oxford, United Kingdomen
dc.contributor.institutionUniversity of Southampton, Southampton, United Kingdomen
dc.contributor.institutionMcMaster University, Hamilton, Canadaen
dc.contributor.institutionEcoles polytechniques federales, , Switzerlanden
kaust.grant.numberKUK-C1-013-04en

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