Gas-Transport-Property Performance of Hybrid Carbon Molecular Sieve−Polymer Materials

Handle URI:
http://hdl.handle.net/10754/598397
Title:
Gas-Transport-Property Performance of Hybrid Carbon Molecular Sieve−Polymer Materials
Authors:
Das, Mita; Perry, John D.; Koros, William J.
Abstract:
High-performance hybrid materials using carbon molecular sieve materials and 6FDA-6FpDA were produced. A detailed analysis of the effects of casting processes and the annealing temperature is reported. Two existing major obstacles, sieve agglomeration and residual stress, were addressed in this work, and subsequently a new membrane formation technique was developed to produce high-performing membranes. The successfully improved interfacial region of the hybrid membranes allows the sieves to increase the selectivity of the membranes above the neat polymer properties. Furthermore, an additional performance enhancement was seen with increased sieve loading in the hybrid membranes, leading to an actual performance above the upper bound for pure polymer membranes. The membranes were also tested under a mixed-gas environment, which further demonstrated promising results. © 2010 American Chemical Society.
Citation:
Das M, Perry JD, Koros WJ (2010) Gas-Transport-Property Performance of Hybrid Carbon Molecular Sieve−Polymer Materials. Ind Eng Chem Res 49: 9310–9321. Available: http://dx.doi.org/10.1021/ie100843r.
Publisher:
American Chemical Society (ACS)
Journal:
Industrial & Engineering Chemistry Research
KAUST Grant Number:
KUS-11-011-21
Issue Date:
6-Oct-2010
DOI:
10.1021/ie100843r
Type:
Article
ISSN:
0888-5885; 1520-5045
Sponsors:
The authors acknowledge financial support from NSF STC under Agreement CHE-9876674 and Award KUS-11-011-21 made by King Abdullah University of Science and Technology (KAUST).
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorDas, Mitaen
dc.contributor.authorPerry, John D.en
dc.contributor.authorKoros, William J.en
dc.date.accessioned2016-02-25T13:20:01Zen
dc.date.available2016-02-25T13:20:01Zen
dc.date.issued2010-10-06en
dc.identifier.citationDas M, Perry JD, Koros WJ (2010) Gas-Transport-Property Performance of Hybrid Carbon Molecular Sieve−Polymer Materials. Ind Eng Chem Res 49: 9310–9321. Available: http://dx.doi.org/10.1021/ie100843r.en
dc.identifier.issn0888-5885en
dc.identifier.issn1520-5045en
dc.identifier.doi10.1021/ie100843ren
dc.identifier.urihttp://hdl.handle.net/10754/598397en
dc.description.abstractHigh-performance hybrid materials using carbon molecular sieve materials and 6FDA-6FpDA were produced. A detailed analysis of the effects of casting processes and the annealing temperature is reported. Two existing major obstacles, sieve agglomeration and residual stress, were addressed in this work, and subsequently a new membrane formation technique was developed to produce high-performing membranes. The successfully improved interfacial region of the hybrid membranes allows the sieves to increase the selectivity of the membranes above the neat polymer properties. Furthermore, an additional performance enhancement was seen with increased sieve loading in the hybrid membranes, leading to an actual performance above the upper bound for pure polymer membranes. The membranes were also tested under a mixed-gas environment, which further demonstrated promising results. © 2010 American Chemical Society.en
dc.description.sponsorshipThe authors acknowledge financial support from NSF STC under Agreement CHE-9876674 and Award KUS-11-011-21 made by King Abdullah University of Science and Technology (KAUST).en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleGas-Transport-Property Performance of Hybrid Carbon Molecular Sieve−Polymer Materialsen
dc.typeArticleen
dc.identifier.journalIndustrial & Engineering Chemistry Researchen
dc.contributor.institutionGeorgia Institute of Technology, Atlanta, United Statesen
dc.contributor.institutionExxonMobil, Irving, United Statesen
kaust.grant.numberKUS-11-011-21en
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