Formation of Methyl Acrylate from CO 2 and Ethylene via Methylation of Nickelalactones

Handle URI:
http://hdl.handle.net/10754/598353
Title:
Formation of Methyl Acrylate from CO 2 and Ethylene via Methylation of Nickelalactones
Authors:
Bruckmeier, Christian; Lehenmeier, Maximilian W.; Reichardt, Robert; Vagin, Sergei; Rieger, Bernhard
Abstract:
The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the β-hydride elimination and the liberation of the acrylate species. © 2010 American Chemical Society.
Citation:
Bruckmeier C, Lehenmeier MW, Reichardt R, Vagin S, Rieger B (2010) Formation of Methyl Acrylate from CO 2 and Ethylene via Methylation of Nickelalactones . Organometallics 29: 2199–2202. Available: http://dx.doi.org/10.1021/om100060y.
Publisher:
American Chemical Society (ACS)
Journal:
Organometallics
Issue Date:
24-May-2010
DOI:
10.1021/om100060y
Type:
Article
ISSN:
0276-7333; 1520-6041
Sponsors:
The financial support of the KAUST (King Abdullah University of Science and Technology) is gratefully acknowledged.
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorBruckmeier, Christianen
dc.contributor.authorLehenmeier, Maximilian W.en
dc.contributor.authorReichardt, Roberten
dc.contributor.authorVagin, Sergeien
dc.contributor.authorRieger, Bernharden
dc.date.accessioned2016-02-25T13:19:14Zen
dc.date.available2016-02-25T13:19:14Zen
dc.date.issued2010-05-24en
dc.identifier.citationBruckmeier C, Lehenmeier MW, Reichardt R, Vagin S, Rieger B (2010) Formation of Methyl Acrylate from CO 2 and Ethylene via Methylation of Nickelalactones . Organometallics 29: 2199–2202. Available: http://dx.doi.org/10.1021/om100060y.en
dc.identifier.issn0276-7333en
dc.identifier.issn1520-6041en
dc.identifier.doi10.1021/om100060yen
dc.identifier.urihttp://hdl.handle.net/10754/598353en
dc.description.abstractThe nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the β-hydride elimination and the liberation of the acrylate species. © 2010 American Chemical Society.en
dc.description.sponsorshipThe financial support of the KAUST (King Abdullah University of Science and Technology) is gratefully acknowledged.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleFormation of Methyl Acrylate from CO 2 and Ethylene via Methylation of Nickelalactonesen
dc.typeArticleen
dc.identifier.journalOrganometallicsen
dc.contributor.institutionTechnische Universitat Munchen, Munich, Germanyen
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