Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data

Handle URI:
http://hdl.handle.net/10754/598204
Title:
Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data
Authors:
Starikov, E.B.; Nordén, B.
Abstract:
Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.
Citation:
Starikov EB, Nordén B (2012) Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data. Chemical Physics Letters 538: 118–120. Available: http://dx.doi.org/10.1016/j.cplett.2012.04.028.
Publisher:
Elsevier BV
Journal:
Chemical Physics Letters
Issue Date:
Jun-2012
DOI:
10.1016/j.cplett.2012.04.028
Type:
Article
ISSN:
0009-2614
Sponsors:
B.N. would like to acknowledge financial support from King Abdullah University of Science and Technology (KAUST).
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorStarikov, E.B.en
dc.contributor.authorNordén, B.en
dc.date.accessioned2016-02-25T13:14:39Zen
dc.date.available2016-02-25T13:14:39Zen
dc.date.issued2012-06en
dc.identifier.citationStarikov EB, Nordén B (2012) Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data. Chemical Physics Letters 538: 118–120. Available: http://dx.doi.org/10.1016/j.cplett.2012.04.028.en
dc.identifier.issn0009-2614en
dc.identifier.doi10.1016/j.cplett.2012.04.028en
dc.identifier.urihttp://hdl.handle.net/10754/598204en
dc.description.abstractEnthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipB.N. would like to acknowledge financial support from King Abdullah University of Science and Technology (KAUST).en
dc.publisherElsevier BVen
dc.titleEntropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental dataen
dc.typeArticleen
dc.identifier.journalChemical Physics Lettersen
dc.contributor.institutionTechnische Universitat Dresden, Dresden, Germanyen
dc.contributor.institutionChalmers University of Technology, Göteborg, Swedenen
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