Electrochemical Characterization of TiO 2 Blocking Layers for Dye-Sensitized Solar Cells

Handle URI:
http://hdl.handle.net/10754/598136
Title:
Electrochemical Characterization of TiO 2 Blocking Layers for Dye-Sensitized Solar Cells
Authors:
Kavan, Ladislav; Tétreault, Nicolas; Moehl, Thomas; Grätzel, Michael
Abstract:
Thin compact layers of TiO2 are grown by thermal oxidation of Ti, by spray pyrolysis, by electrochemical deposition, and by atomic layer deposition. These layers are used in dye-sensitized solar cells to prevent recombination of electrons from the substrate (FTO or Ti) with the hole-conducting medium at this interface. The quality of blocking is evaluated electrochemically by methylviologen, ferro/ferricyanide, and spiro-OMeTAD as the model redox probes. Two types of pinholes in the blocking layers are classified, and their effective area is quantified. Frequency-independent Mott-Schottky plots are fitted from electrochemical impedance spectroscopy. Certain films of the thicknesses of several nanometers allow distinguishing the depletion layer formation both in the TiO2 film and in the FTO substrate underneath the titania film. The excellent blocking function of thermally oxidized Ti, electrodeposited film (60 nm), and atomic-layer-deposited films (>6 nm) is documented by the relative pinhole area of less than 1%. However, the blocking behavior of electrodeposited and atomic-layer-deposited films is strongly reduced upon calcination at 500 °C. The blocking function of spray-pyrolyzed films is less good but also less sensitive to calcination. The thermally oxidized Ti is well blocking and insensitive to calcination. © 2014 American Chemical Society.
Citation:
Kavan L, Tétreault N, Moehl T, Grätzel M (2014) Electrochemical Characterization of TiO 2 Blocking Layers for Dye-Sensitized Solar Cells . The Journal of Physical Chemistry C 118: 16408–16418. Available: http://dx.doi.org/10.1021/jp4103614.
Publisher:
American Chemical Society (ACS)
Journal:
The Journal of Physical Chemistry C
KAUST Grant Number:
KUS-C1-015-21
Issue Date:
31-Jul-2014
DOI:
10.1021/jp4103614
Type:
Article
ISSN:
1932-7447; 1932-7455
Sponsors:
This work was supported by the EC 7th FP project SANS (contract no. NMP-246124), by the COST Action CM1104, and by the Grant Agency of the Czech Republic (contract no. 13-07724S). This work was also partially supported by the ECR Advanced Grant Agreement no. 247404 under the CE-Mesolight project and by the Center for Advanced Molecular Photovoltaics (Award No KUS-C1-015-21), made by King Abdullah University of Science and Technology (KAUST).
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Full metadata record

DC FieldValue Language
dc.contributor.authorKavan, Ladislaven
dc.contributor.authorTétreault, Nicolasen
dc.contributor.authorMoehl, Thomasen
dc.contributor.authorGrätzel, Michaelen
dc.date.accessioned2016-02-25T13:13:21Zen
dc.date.available2016-02-25T13:13:21Zen
dc.date.issued2014-07-31en
dc.identifier.citationKavan L, Tétreault N, Moehl T, Grätzel M (2014) Electrochemical Characterization of TiO 2 Blocking Layers for Dye-Sensitized Solar Cells . The Journal of Physical Chemistry C 118: 16408–16418. Available: http://dx.doi.org/10.1021/jp4103614.en
dc.identifier.issn1932-7447en
dc.identifier.issn1932-7455en
dc.identifier.doi10.1021/jp4103614en
dc.identifier.urihttp://hdl.handle.net/10754/598136en
dc.description.abstractThin compact layers of TiO2 are grown by thermal oxidation of Ti, by spray pyrolysis, by electrochemical deposition, and by atomic layer deposition. These layers are used in dye-sensitized solar cells to prevent recombination of electrons from the substrate (FTO or Ti) with the hole-conducting medium at this interface. The quality of blocking is evaluated electrochemically by methylviologen, ferro/ferricyanide, and spiro-OMeTAD as the model redox probes. Two types of pinholes in the blocking layers are classified, and their effective area is quantified. Frequency-independent Mott-Schottky plots are fitted from electrochemical impedance spectroscopy. Certain films of the thicknesses of several nanometers allow distinguishing the depletion layer formation both in the TiO2 film and in the FTO substrate underneath the titania film. The excellent blocking function of thermally oxidized Ti, electrodeposited film (60 nm), and atomic-layer-deposited films (>6 nm) is documented by the relative pinhole area of less than 1%. However, the blocking behavior of electrodeposited and atomic-layer-deposited films is strongly reduced upon calcination at 500 °C. The blocking function of spray-pyrolyzed films is less good but also less sensitive to calcination. The thermally oxidized Ti is well blocking and insensitive to calcination. © 2014 American Chemical Society.en
dc.description.sponsorshipThis work was supported by the EC 7th FP project SANS (contract no. NMP-246124), by the COST Action CM1104, and by the Grant Agency of the Czech Republic (contract no. 13-07724S). This work was also partially supported by the ECR Advanced Grant Agreement no. 247404 under the CE-Mesolight project and by the Center for Advanced Molecular Photovoltaics (Award No KUS-C1-015-21), made by King Abdullah University of Science and Technology (KAUST).en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleElectrochemical Characterization of TiO 2 Blocking Layers for Dye-Sensitized Solar Cellsen
dc.typeArticleen
dc.identifier.journalThe Journal of Physical Chemistry Cen
dc.contributor.institutionJ. Heyrovsky Institute of Physical Chemistry of the Academy of Sciences of the Czech Republic, Prague, Czech Republicen
dc.contributor.institutionEcoles polytechniques federales, , Switzerlanden
kaust.grant.numberKUS-C1-015-21en
kaust.grant.fundedcenterCenter for Advanced Molecular Photovoltaics (CAMP)en
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