Handle URI:
http://hdl.handle.net/10754/598098
Title:
Efficient and Highly Aldehyde Selective Wacker Oxidation
Authors:
Teo, Peili; Wickens, Zachary K.; Dong, Guangbin; Grubbs, Robert H.
Abstract:
A method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl 2(MeCN) 2, 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates. © 2012 American Chemical Society.
Citation:
Teo P, Wickens ZK, Dong G, Grubbs RH (2012) Efficient and Highly Aldehyde Selective Wacker Oxidation. Organic Letters 14: 3237–3239. Available: http://dx.doi.org/10.1021/ol301240g.
Publisher:
American Chemical Society (ACS)
Journal:
Organic Letters
Issue Date:
6-Jul-2012
DOI:
10.1021/ol301240g
PubMed ID:
22694293
Type:
Article
ISSN:
1523-7060; 1523-7052
Sponsors:
We gratefully acknowledge financial support from King Abdullah University of Science and Technology Centre in Development, King Fahd University of Petroleum and Minerals, and the NSF. G.D. thanks the Camille and Henry Dreyfus Foundation for a postdoctoral fellowship.
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Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorTeo, Peilien
dc.contributor.authorWickens, Zachary K.en
dc.contributor.authorDong, Guangbinen
dc.contributor.authorGrubbs, Robert H.en
dc.date.accessioned2016-02-25T13:12:38Zen
dc.date.available2016-02-25T13:12:38Zen
dc.date.issued2012-07-06en
dc.identifier.citationTeo P, Wickens ZK, Dong G, Grubbs RH (2012) Efficient and Highly Aldehyde Selective Wacker Oxidation. Organic Letters 14: 3237–3239. Available: http://dx.doi.org/10.1021/ol301240g.en
dc.identifier.issn1523-7060en
dc.identifier.issn1523-7052en
dc.identifier.pmid22694293en
dc.identifier.doi10.1021/ol301240gen
dc.identifier.urihttp://hdl.handle.net/10754/598098en
dc.description.abstractA method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl 2(MeCN) 2, 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates. © 2012 American Chemical Society.en
dc.description.sponsorshipWe gratefully acknowledge financial support from King Abdullah University of Science and Technology Centre in Development, King Fahd University of Petroleum and Minerals, and the NSF. G.D. thanks the Camille and Henry Dreyfus Foundation for a postdoctoral fellowship.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleEfficient and Highly Aldehyde Selective Wacker Oxidationen
dc.typeArticleen
dc.identifier.journalOrganic Lettersen
dc.contributor.institutionCalifornia Institute of Technology, Pasadena, United Statesen
dc.contributor.institutionInstitute of Chemical and Engineering Sciences, Singapore City, Singaporeen
dc.contributor.institutionUniversity of Texas at Austin, Austin, United Statesen
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