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Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand

Handle URI:
http://hdl.handle.net/10754/597841
Title:
Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand
Authors:
Wang, Xiaofang; Xue, Ming; Wu, Gang; Pan, Ying; Qiu, Shilun
Abstract:
© 2015 Elsevier B.V. All Rights Reserved. The self-assembly of a prominent ligand, 5-(4-(1H-tetrazolyl)phen)isophthalic acid (H3TZPI), with Zn2 +/Cu2 + centres generates two new MOFs, [Zn2(TZPI)(μ3-OH)(H2O)2]·2H2O (JUC-161) and [Cu(HTZPI)(μ2-H2O)0.5(H2O)1.5]·5(H2O) (JUC-162). JUC-161 exhibits fascinating three-dimensional structures containing rectangular channels with dimensions of 6.5 × 3.0 Å2, and JUC-162 displays 3D supramolecular structures with 12.5 × 14.6 Å2 hexagonal channels. The observed structural diversity in these frameworks is due to the two distinct coordinating moieties of the H3TZPI ligand. The photoluminescence of JUC-161 and the magnetic properties of JUC-162 are also measured at room temperature. Photoluminescence investigations reveal that JUC-161 displays a strong main emission spectrum peak at 388 nm. JUC-162 is found to exhibit an antiferromagnetic interaction between Cu2 + ions.
Citation:
Wang X, Xue M, Wu G, Pan Y, Qiu S (2016) Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand. Inorganic Chemistry Communications 64: 31–34. Available: http://dx.doi.org/10.1016/j.inoche.2015.12.004.
Publisher:
Elsevier BV
Journal:
Inorganic Chemistry Communications
KAUST Grant Number:
CRG-1-2012-LAI-009
Issue Date:
Feb-2016
DOI:
10.1016/j.inoche.2015.12.004
Type:
Article
ISSN:
1387-7003
Sponsors:
This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21471066, 21571076), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012).
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Xiaofangen
dc.contributor.authorXue, Mingen
dc.contributor.authorWu, Gangen
dc.contributor.authorPan, Yingen
dc.contributor.authorQiu, Shilunen
dc.date.accessioned2016-02-25T12:57:37Zen
dc.date.available2016-02-25T12:57:37Zen
dc.date.issued2016-02en
dc.identifier.citationWang X, Xue M, Wu G, Pan Y, Qiu S (2016) Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand. Inorganic Chemistry Communications 64: 31–34. Available: http://dx.doi.org/10.1016/j.inoche.2015.12.004.en
dc.identifier.issn1387-7003en
dc.identifier.doi10.1016/j.inoche.2015.12.004en
dc.identifier.urihttp://hdl.handle.net/10754/597841en
dc.description.abstract© 2015 Elsevier B.V. All Rights Reserved. The self-assembly of a prominent ligand, 5-(4-(1H-tetrazolyl)phen)isophthalic acid (H3TZPI), with Zn2 +/Cu2 + centres generates two new MOFs, [Zn2(TZPI)(μ3-OH)(H2O)2]·2H2O (JUC-161) and [Cu(HTZPI)(μ2-H2O)0.5(H2O)1.5]·5(H2O) (JUC-162). JUC-161 exhibits fascinating three-dimensional structures containing rectangular channels with dimensions of 6.5 × 3.0 Å2, and JUC-162 displays 3D supramolecular structures with 12.5 × 14.6 Å2 hexagonal channels. The observed structural diversity in these frameworks is due to the two distinct coordinating moieties of the H3TZPI ligand. The photoluminescence of JUC-161 and the magnetic properties of JUC-162 are also measured at room temperature. Photoluminescence investigations reveal that JUC-161 displays a strong main emission spectrum peak at 388 nm. JUC-162 is found to exhibit an antiferromagnetic interaction between Cu2 + ions.en
dc.description.sponsorshipThis work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21471066, 21571076), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012).en
dc.publisherElsevier BVen
dc.subjectConfigurationsen
dc.subjectLuminescenceen
dc.subjectMagnetismen
dc.subjectMetal-organic frameworksen
dc.titleConstructing two new crystalline metal–organic frameworks based on a mixed-donor liganden
dc.typeArticleen
dc.identifier.journalInorganic Chemistry Communicationsen
dc.contributor.institutionJilin University, Changchun, Chinaen
kaust.grant.numberCRG-1-2012-LAI-009en
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