CO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy

Handle URI:
http://hdl.handle.net/10754/597786
Title:
CO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy
Authors:
Park, Youngjune; Shin, Dolly; Jang, Young Nam; Park, Ah-Hyung Alissa
Abstract:
Novel nanoparticle organic hybrid materials (NOHMs), which are comprised of organic oligomers or polymers tethered to an inorganic nanosized cores of various sizes, have been synthesized, and their solvating property for CO 2 was investigated using attenuated total reflectance (ATR) Fourier transform infrared (FT-IR) spectroscopy. Simultaneous measurements of CO 2 capture capacity and swelling behaviors of polyetheramine (Jeffamine M-2070) and its corresponding NOHMs (NOHM-I-PE2070) were reported at temperatures of (298, 308, 323 and 353) K and CO 2 pressure conditions ranging from (0 to 5.5) MPa. The polymeric canopy, or polymer bound to the nanoparticle surface, showed significantly less swelling behavior with enhanced or comparable CO 2 capture capacity compared to pure unbound polyetheramine. © 2011 American Chemical Society.
Citation:
Park Y, Shin D, Jang YN, Park A-HA (2012) CO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy . J Chem Eng Data 57: 40–45. Available: http://dx.doi.org/10.1021/je200623b.
Publisher:
American Chemical Society (ACS)
Journal:
Journal of Chemical & Engineering Data
KAUST Grant Number:
KUS-C1-018-02
Issue Date:
12-Jan-2012
DOI:
10.1021/je200623b
Type:
Article
ISSN:
0021-9568; 1520-5134
Sponsors:
This publication was based on work supported in part by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST), and the Utilization and Sequestration of CO<INF>2</INF> using Industrial Minerals Program by Korea Institute of Geoscience & Mineral Resources (KIGAM).
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Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorPark, Youngjuneen
dc.contributor.authorShin, Dollyen
dc.contributor.authorJang, Young Namen
dc.contributor.authorPark, Ah-Hyung Alissaen
dc.date.accessioned2016-02-25T12:56:41Zen
dc.date.available2016-02-25T12:56:41Zen
dc.date.issued2012-01-12en
dc.identifier.citationPark Y, Shin D, Jang YN, Park A-HA (2012) CO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy . J Chem Eng Data 57: 40–45. Available: http://dx.doi.org/10.1021/je200623b.en
dc.identifier.issn0021-9568en
dc.identifier.issn1520-5134en
dc.identifier.doi10.1021/je200623ben
dc.identifier.urihttp://hdl.handle.net/10754/597786en
dc.description.abstractNovel nanoparticle organic hybrid materials (NOHMs), which are comprised of organic oligomers or polymers tethered to an inorganic nanosized cores of various sizes, have been synthesized, and their solvating property for CO 2 was investigated using attenuated total reflectance (ATR) Fourier transform infrared (FT-IR) spectroscopy. Simultaneous measurements of CO 2 capture capacity and swelling behaviors of polyetheramine (Jeffamine M-2070) and its corresponding NOHMs (NOHM-I-PE2070) were reported at temperatures of (298, 308, 323 and 353) K and CO 2 pressure conditions ranging from (0 to 5.5) MPa. The polymeric canopy, or polymer bound to the nanoparticle surface, showed significantly less swelling behavior with enhanced or comparable CO 2 capture capacity compared to pure unbound polyetheramine. © 2011 American Chemical Society.en
dc.description.sponsorshipThis publication was based on work supported in part by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST), and the Utilization and Sequestration of CO<INF>2</INF> using Industrial Minerals Program by Korea Institute of Geoscience & Mineral Resources (KIGAM).en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleCO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopyen
dc.typeArticleen
dc.identifier.journalJournal of Chemical & Engineering Dataen
dc.contributor.institutionColumbia University in the City of New York, New York, United Statesen
dc.contributor.institutionKorea Institute of Geoscience and Mineral Resources, Daejeon, South Koreaen
kaust.grant.numberKUS-C1-018-02en
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