Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework

Handle URI:
http://hdl.handle.net/10754/597728
Title:
Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework
Authors:
Huang, Lin; Xue, Ming; Song, Qingshan; Chen, Siru; Pan, Ying; Qiu, Shilun
Abstract:
A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.
Citation:
Huang L, Xue M, Song Q, Chen S, Pan Y, et al. (2014) Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework. Inorganic Chemistry Communications 46: 9–12. Available: http://dx.doi.org/10.1016/j.inoche.2014.04.026.
Publisher:
Elsevier BV
Journal:
Inorganic Chemistry Communications
KAUST Grant Number:
CRG-1-2012-LAI-009
Issue Date:
Aug-2014
DOI:
10.1016/j.inoche.2014.04.026
Type:
Article
ISSN:
1387-7003
Sponsors:
This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21101072, 21261130584, 91022030), "111" project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).
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Full metadata record

DC FieldValue Language
dc.contributor.authorHuang, Linen
dc.contributor.authorXue, Mingen
dc.contributor.authorSong, Qingshanen
dc.contributor.authorChen, Siruen
dc.contributor.authorPan, Yingen
dc.contributor.authorQiu, Shilunen
dc.date.accessioned2016-02-25T12:55:39Zen
dc.date.available2016-02-25T12:55:39Zen
dc.date.issued2014-08en
dc.identifier.citationHuang L, Xue M, Song Q, Chen S, Pan Y, et al. (2014) Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework. Inorganic Chemistry Communications 46: 9–12. Available: http://dx.doi.org/10.1016/j.inoche.2014.04.026.en
dc.identifier.issn1387-7003en
dc.identifier.doi10.1016/j.inoche.2014.04.026en
dc.identifier.urihttp://hdl.handle.net/10754/597728en
dc.description.abstractA new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.en
dc.description.sponsorshipThis work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21101072, 21261130584, 91022030), "111" project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).en
dc.publisherElsevier BVen
dc.subjectCarbon dioxideen
dc.subjectMixed liganden
dc.subjectSelective adsorptionen
dc.subjectStabilityen
dc.subjectZeolitic Imidazolate Frameworksen
dc.titleCarbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Frameworken
dc.typeArticleen
dc.identifier.journalInorganic Chemistry Communicationsen
dc.contributor.institutionJilin University, Changchun, Chinaen
kaust.grant.numberCRG-1-2012-LAI-009en
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