Applications versus properties of Mg–Al layered double hydroxides provided by their syntheses methods: Alkoxide and alkoxide-free sol–gel syntheses and hydrothermal precipitation

Handle URI:
http://hdl.handle.net/10754/597600
Title:
Applications versus properties of Mg–Al layered double hydroxides provided by their syntheses methods: Alkoxide and alkoxide-free sol–gel syntheses and hydrothermal precipitation
Authors:
Chubar, Natalia; Gerda, Vasyl; Megantari, Otty; Mičušík, Matej; Omastova, Maria; Heister, Katja; Man, Pascal; Fraissard, Jacques
Abstract:
A tremendous number of studies have examined layered double hydroxides (LDH) for their technological applications in the ion exchange removal of toxic ions, recovery of valuable substances, catalysis, CO2 capture, as a layered host for storage/delivery of biologically active molecules, additives to plastics and building materials, and other functions. Numerous publications always conclude that the materials (prepared, as a rule, using the oldest synthesis method) are very promising for each investigated application; however, the main chemical industries producing these materials advertise them mainly (or only) as plastic additives. The authors performed extensive research using many of the appropriate methods to compare the structure, surface and adsorptive properties of three Mg-Al LHDs produced by advanced synthesis methods. One industrial sample (by Sasol, Germany) prepared by the alkoxide sol-gel method and two novel Mg-Al LDHs synthesised in-house by alkoxide-free sol-gel and hydrothermal precipitation approaches were investigated. Reasons for the very different adsorptive selectivity of the three LDHs towards arsenate, selenate, phosphate, arsenite and selenite have been provided, highlighting the role of speciation of the interlayer carbonate, aluminium, magnesium, interlayer hydration and moisture content in the adsorptive selectivity towards each toxic anion. This work is the first report presenting the regularities of the LDHs structure, surface and anion exchange properties as a function of their syntheses method. It establishes the links to potential technological applications of each investigated LDH and explains the necessary properties required to make the technological application cost-effective and efficient. The paper might accelerate industrial applications of these advanced materials. © 2013 Elsevier B.V.
Citation:
Chubar N, Gerda V, Megantari O, Mičušík M, Omastova M, et al. (2013) Applications versus properties of Mg–Al layered double hydroxides provided by their syntheses methods: Alkoxide and alkoxide-free sol–gel syntheses and hydrothermal precipitation. Chemical Engineering Journal 234: 284–299. Available: http://dx.doi.org/10.1016/j.cej.2013.08.097.
Publisher:
Elsevier BV
Journal:
Chemical Engineering Journal
KAUST Grant Number:
KUK-C1-017-12
Issue Date:
Dec-2013
DOI:
10.1016/j.cej.2013.08.097
Type:
Article
ISSN:
1385-8947
Sponsors:
A considerable portion of the work was funded by King Abdullah University of Science and Technology (KAUST) via the Global Research Partnership Programme, Award No. KUK-C1-017-12. The authors thank Ms Denise Gilmour (Strathclyde University) for her assistance with the CNHS analysis. The authors also thank Mr. Thomas Konig (Utrecht University) for providing the commercial sample of Mg-Al-CO<INF>3</INF> LDH (Mg-Al ASG) for the studies and fruitful discussion of the results. The authors are grateful to Ms. Helen de Waard, Ms. Dineke van de Meent-Olieman, Mr. Pieter Kleingeld and Mr. Ton Zalm (Utrecht University) for excellent technical support during their research. The authors thank the anonymous Reviewers who helped them to improve this work considerably.
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Full metadata record

DC FieldValue Language
dc.contributor.authorChubar, Nataliaen
dc.contributor.authorGerda, Vasylen
dc.contributor.authorMegantari, Ottyen
dc.contributor.authorMičušík, Matejen
dc.contributor.authorOmastova, Mariaen
dc.contributor.authorHeister, Katjaen
dc.contributor.authorMan, Pascalen
dc.contributor.authorFraissard, Jacquesen
dc.date.accessioned2016-02-25T12:42:50Zen
dc.date.available2016-02-25T12:42:50Zen
dc.date.issued2013-12en
dc.identifier.citationChubar N, Gerda V, Megantari O, Mičušík M, Omastova M, et al. (2013) Applications versus properties of Mg–Al layered double hydroxides provided by their syntheses methods: Alkoxide and alkoxide-free sol–gel syntheses and hydrothermal precipitation. Chemical Engineering Journal 234: 284–299. Available: http://dx.doi.org/10.1016/j.cej.2013.08.097.en
dc.identifier.issn1385-8947en
dc.identifier.doi10.1016/j.cej.2013.08.097en
dc.identifier.urihttp://hdl.handle.net/10754/597600en
dc.description.abstractA tremendous number of studies have examined layered double hydroxides (LDH) for their technological applications in the ion exchange removal of toxic ions, recovery of valuable substances, catalysis, CO2 capture, as a layered host for storage/delivery of biologically active molecules, additives to plastics and building materials, and other functions. Numerous publications always conclude that the materials (prepared, as a rule, using the oldest synthesis method) are very promising for each investigated application; however, the main chemical industries producing these materials advertise them mainly (or only) as plastic additives. The authors performed extensive research using many of the appropriate methods to compare the structure, surface and adsorptive properties of three Mg-Al LHDs produced by advanced synthesis methods. One industrial sample (by Sasol, Germany) prepared by the alkoxide sol-gel method and two novel Mg-Al LDHs synthesised in-house by alkoxide-free sol-gel and hydrothermal precipitation approaches were investigated. Reasons for the very different adsorptive selectivity of the three LDHs towards arsenate, selenate, phosphate, arsenite and selenite have been provided, highlighting the role of speciation of the interlayer carbonate, aluminium, magnesium, interlayer hydration and moisture content in the adsorptive selectivity towards each toxic anion. This work is the first report presenting the regularities of the LDHs structure, surface and anion exchange properties as a function of their syntheses method. It establishes the links to potential technological applications of each investigated LDH and explains the necessary properties required to make the technological application cost-effective and efficient. The paper might accelerate industrial applications of these advanced materials. © 2013 Elsevier B.V.en
dc.description.sponsorshipA considerable portion of the work was funded by King Abdullah University of Science and Technology (KAUST) via the Global Research Partnership Programme, Award No. KUK-C1-017-12. The authors thank Ms Denise Gilmour (Strathclyde University) for her assistance with the CNHS analysis. The authors also thank Mr. Thomas Konig (Utrecht University) for providing the commercial sample of Mg-Al-CO<INF>3</INF> LDH (Mg-Al ASG) for the studies and fruitful discussion of the results. The authors are grateful to Ms. Helen de Waard, Ms. Dineke van de Meent-Olieman, Mr. Pieter Kleingeld and Mr. Ton Zalm (Utrecht University) for excellent technical support during their research. The authors thank the anonymous Reviewers who helped them to improve this work considerably.en
dc.publisherElsevier BVen
dc.subjectHydrothermal precipitationen
dc.subjectIon exchange adsorptionen
dc.subjectMg-Al layered double hydroxidesen
dc.subjectSol-gel synthesisen
dc.subjectSustainable materialsen
dc.subjectToxic anionsen
dc.titleApplications versus properties of Mg–Al layered double hydroxides provided by their syntheses methods: Alkoxide and alkoxide-free sol–gel syntheses and hydrothermal precipitationen
dc.typeArticleen
dc.identifier.journalChemical Engineering Journalen
dc.contributor.institutionUtrecht University, Utrecht, Netherlandsen
dc.contributor.institutionGlasgow Caledonian University, Glasgow, United Kingdomen
dc.contributor.institutionTaras Shevchenko National University of Kyiv, Kiev, Ukraineen
dc.contributor.institutionPolymer Institute of Slovak Academy of Sciences, Bratislava, Slovakiaen
dc.contributor.institutionTechnische Universitat Munchen, Munich, Germanyen
dc.contributor.institutionUniversite Pierre et Marie Curie, Paris, Franceen
kaust.grant.numberKUK-C1-017-12en
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