Ambient-Processed Colloidal Quantum Dot Solar Cells via Individual Pre-Encapsulation of Nanoparticles

Handle URI:
http://hdl.handle.net/10754/597496
Title:
Ambient-Processed Colloidal Quantum Dot Solar Cells via Individual Pre-Encapsulation of Nanoparticles
Authors:
Debnath, Ratan; Tang, Jiang; Barkhouse, D. Aaron; Wang, Xihua; Pattantyus-Abraham, Andras G.; Brzozowski, Lukasz; Levina, Larissa; Sargent, Edward H.
Abstract:
We report colloidal quantum dot solar cells fabricated under ambient atmosphere with an active area of 2.9 mm2 that exhibit 3.6% solar power conversion efficiency. The devices are based on PbS tuned via the quantum size effect to have a first excitonic peak at 950 nm. Because the formation of native oxides and sulfates on PbS leads to p-type doping and deep trap formation and because such dopants and traps dramatically influence device performance, prior reports of colloidal quantum dot solar cells have insisted on processing under an inert atmosphere. Here we report a novel ligand strategy in which we first encapsulate the quantum dots in the solution phase with the aid of a strongly bound N-2,4,6-trimethylphenyl-N-methyldithiocarbamate ligand. This allows us to carry out film formation and all subsequent device fabrication under an air atmosphere. © 2010 American Chemical Society.
Citation:
Debnath R, Tang J, Barkhouse DA, Wang X, Pattantyus-Abraham AG, et al. (2010) Ambient-Processed Colloidal Quantum Dot Solar Cells via Individual Pre-Encapsulation of Nanoparticles. Journal of the American Chemical Society 132: 5952–5953. Available: http://dx.doi.org/10.1021/ja1013695.
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
KAUST Grant Number:
KUS-II-009-21
Issue Date:
5-May-2010
DOI:
10.1021/ja1013695
PubMed ID:
20387887
Type:
Article
ISSN:
0002-7863; 1520-5126
Sponsors:
This research was supported by the Natural Sciences and Engineering Research Council (NSERC) of Canada and in part by Award KUS-II-009-21 from King Abdullah University of Science and Technology (KAUST). R.D. and D.A.B acknowledge financial support through e8 and NSERC fellowships, respectively.
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorDebnath, Ratanen
dc.contributor.authorTang, Jiangen
dc.contributor.authorBarkhouse, D. Aaronen
dc.contributor.authorWang, Xihuaen
dc.contributor.authorPattantyus-Abraham, Andras G.en
dc.contributor.authorBrzozowski, Lukaszen
dc.contributor.authorLevina, Larissaen
dc.contributor.authorSargent, Edward H.en
dc.date.accessioned2016-02-25T12:40:52Zen
dc.date.available2016-02-25T12:40:52Zen
dc.date.issued2010-05-05en
dc.identifier.citationDebnath R, Tang J, Barkhouse DA, Wang X, Pattantyus-Abraham AG, et al. (2010) Ambient-Processed Colloidal Quantum Dot Solar Cells via Individual Pre-Encapsulation of Nanoparticles. Journal of the American Chemical Society 132: 5952–5953. Available: http://dx.doi.org/10.1021/ja1013695.en
dc.identifier.issn0002-7863en
dc.identifier.issn1520-5126en
dc.identifier.pmid20387887en
dc.identifier.doi10.1021/ja1013695en
dc.identifier.urihttp://hdl.handle.net/10754/597496en
dc.description.abstractWe report colloidal quantum dot solar cells fabricated under ambient atmosphere with an active area of 2.9 mm2 that exhibit 3.6% solar power conversion efficiency. The devices are based on PbS tuned via the quantum size effect to have a first excitonic peak at 950 nm. Because the formation of native oxides and sulfates on PbS leads to p-type doping and deep trap formation and because such dopants and traps dramatically influence device performance, prior reports of colloidal quantum dot solar cells have insisted on processing under an inert atmosphere. Here we report a novel ligand strategy in which we first encapsulate the quantum dots in the solution phase with the aid of a strongly bound N-2,4,6-trimethylphenyl-N-methyldithiocarbamate ligand. This allows us to carry out film formation and all subsequent device fabrication under an air atmosphere. © 2010 American Chemical Society.en
dc.description.sponsorshipThis research was supported by the Natural Sciences and Engineering Research Council (NSERC) of Canada and in part by Award KUS-II-009-21 from King Abdullah University of Science and Technology (KAUST). R.D. and D.A.B acknowledge financial support through e8 and NSERC fellowships, respectively.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleAmbient-Processed Colloidal Quantum Dot Solar Cells via Individual Pre-Encapsulation of Nanoparticlesen
dc.typeArticleen
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionUniversity of Toronto, Toronto, Canadaen
kaust.grant.numberKUS-II-009-21en

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