A Toolbox of Solid-State NMR Experiments for the Characterization of Soft Organic Nanomaterials

Handle URI:
http://hdl.handle.net/10754/597175
Title:
A Toolbox of Solid-State NMR Experiments for the Characterization of Soft Organic Nanomaterials
Authors:
Straasø, Lasse Arnt; Saleem, Qasim; Hansen, Michael Ryan
Abstract:
Determining how organic molecules self-assemble into a solid material is a challenging and demanding task if a single crystal of the material cannot be produced. Solid-state NMR spectroscopy offers access to such molecular details via an appropriate selection of techniques. This report gives a selected overview of 1D and 2D solid-state NMR techniques for elucidating the structure of soft organic solids. We focus on how the solid-state NMR techniques are designed from the perspective of the different nuclear interactions, using average Hamiltonian theory and product operators. We also introduce recent methods for quantification and reduction of experimental artifacts. Finally, we highlight how the solid-state NMR techniques can be applied to soft organic materials by reviewing recent applications to semicrystalline polymers, π-conjugated polymers, natural silk, and graphene-related materials.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Solar and Photovoltaic Engineering Research Center (SPERC)
Citation:
Straasø, L.A., Saleem, Q. and Hansen, M.R., 2016. A Toolbox of Solid-State NMR Experiments for the Characterization of Soft Organic Nanomaterials. Annual Reports on NMR Spectroscopy.
Publisher:
Elsevier BV
Journal:
Annual Reports on NMR Spectroscopy
Issue Date:
2-Feb-2016
DOI:
10.1016/bs.arnmr.2015.12.001
Type:
Article
ISSN:
0066-4103
Additional Links:
http://www.sciencedirect.com/science/article/pii/S006641031500068X
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorStraasø, Lasse Arnten
dc.contributor.authorSaleem, Qasimen
dc.contributor.authorHansen, Michael Ryanen
dc.date.accessioned2016-02-25T08:59:55Zen
dc.date.available2016-02-25T08:59:55Zen
dc.date.issued2016-02-02en
dc.identifier.citationStraasø, L.A., Saleem, Q. and Hansen, M.R., 2016. A Toolbox of Solid-State NMR Experiments for the Characterization of Soft Organic Nanomaterials. Annual Reports on NMR Spectroscopy.en
dc.identifier.issn0066-4103en
dc.identifier.doi10.1016/bs.arnmr.2015.12.001en
dc.identifier.urihttp://hdl.handle.net/10754/597175en
dc.description.abstractDetermining how organic molecules self-assemble into a solid material is a challenging and demanding task if a single crystal of the material cannot be produced. Solid-state NMR spectroscopy offers access to such molecular details via an appropriate selection of techniques. This report gives a selected overview of 1D and 2D solid-state NMR techniques for elucidating the structure of soft organic solids. We focus on how the solid-state NMR techniques are designed from the perspective of the different nuclear interactions, using average Hamiltonian theory and product operators. We also introduce recent methods for quantification and reduction of experimental artifacts. Finally, we highlight how the solid-state NMR techniques can be applied to soft organic materials by reviewing recent applications to semicrystalline polymers, π-conjugated polymers, natural silk, and graphene-related materials.en
dc.language.isoenen
dc.publisherElsevier BVen
dc.relation.urlhttp://www.sciencedirect.com/science/article/pii/S006641031500068Xen
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in Annual Reports on NMR Spectroscopy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Annual Reports on NMR Spectroscopy, 2 February 2016. DOI: 10.1016/bs.arnmr.2015.12.001en
dc.subjectOrganic solidsen
dc.subject2D NMR techniquesen
dc.subjectNMR interactionsen
dc.subjectNMR theory and Hamiltoniansen
dc.subjectAverage Hamiltonian theoryen
dc.subjectProduct operatorsen
dc.subjectPolymersen
dc.subjectNatural silken
dc.subjectπ-Conjugated polymersen
dc.subjectGraphene-related materialsen
dc.titleA Toolbox of Solid-State NMR Experiments for the Characterization of Soft Organic Nanomaterialsen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.identifier.journalAnnual Reports on NMR Spectroscopyen
dc.eprint.versionPost-printen
dc.contributor.institutionInterdisciplinary Nanoscience Center (iNANO), Aarhus University, Aarhus C, Denmarken
dc.contributor.institutionInstitute of Physical Chemistry, Westfälische Wilhelms-Universität Münster, Münster, Germanyen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorSaleem, Qasimen
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