Synthesis and characterization of a novel laser ablation sensitive triazene incorporated epoxy resin

Handle URI:
http://hdl.handle.net/10754/594179
Title:
Synthesis and characterization of a novel laser ablation sensitive triazene incorporated epoxy resin
Authors:
Patole, Archana S.; Hyeon, Jeong min; Hyun, Jung Mn; Kim, Tae Ho; Patole, Shashikant P.; Hong, Dae Jo; Lee, Chang Bo; Choi, Cheol Ho
Abstract:
New triazene monomer was synthesized and further employed as a crosslinking agent partner with epoxy matrix using ethyl methyl imidazole as a curing agent in order to investigate the effect of triazene moieties on polymeric properties for laser ablation application. The synthesized triazene monomer was characterized by analytical and spectroscopic methods, while the surface morphology of resist after laser ablation was visualized by optical laser scanning images and scanning electron microscopy. Thermogravimetrical investigations indicate the loss of nitrogen being the initial thermal decomposition step and exhibit sufficient stabilities for the requirements for laser ablation application. Fourier transform infra-red, nuclear magnetic resonance, and gas chromatography analyses showed the successful synthesis of triazene. The ablation results from the optical laser scanning images revealed that the etching depth could be controlled by varying the concentration of triazene monomer in the formulation of epoxy. The shear strength analysis revealed that that the shear strength increased with increasing the amount of triazene in the formulation of direct ablation sensitive resist. © 2014 The Korean Institute of Metals and Materials and Springer Science+Business Media Dordrecht.
KAUST Department:
Physical Sciences and Engineering (PSE) Division
Citation:
Patole AS, Hyeon J, Hyun J-M, Kim T-H, Patole SP, et al. (2014) Synthesis and characterization of a novel laser ablation sensitive triazene incorporated epoxy resin. Electron Mater Lett 10: 173–182. Available: http://dx.doi.org/10.1007/s13391-013-3020-7.
Publisher:
Springer Nature
Journal:
Electronic Materials Letters
Issue Date:
Jan-2014
DOI:
10.1007/s13391-013-3020-7
Type:
Article
ISSN:
1738-8090; 2093-6788
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorPatole, Archana S.en
dc.contributor.authorHyeon, Jeong minen
dc.contributor.authorHyun, Jung Mnen
dc.contributor.authorKim, Tae Hoen
dc.contributor.authorPatole, Shashikant P.en
dc.contributor.authorHong, Dae Joen
dc.contributor.authorLee, Chang Boen
dc.contributor.authorChoi, Cheol Hoen
dc.date.accessioned2016-01-19T13:23:16Zen
dc.date.available2016-01-19T13:23:16Zen
dc.date.issued2014-01en
dc.identifier.citationPatole AS, Hyeon J, Hyun J-M, Kim T-H, Patole SP, et al. (2014) Synthesis and characterization of a novel laser ablation sensitive triazene incorporated epoxy resin. Electron Mater Lett 10: 173–182. Available: http://dx.doi.org/10.1007/s13391-013-3020-7.en
dc.identifier.issn1738-8090en
dc.identifier.issn2093-6788en
dc.identifier.doi10.1007/s13391-013-3020-7en
dc.identifier.urihttp://hdl.handle.net/10754/594179en
dc.description.abstractNew triazene monomer was synthesized and further employed as a crosslinking agent partner with epoxy matrix using ethyl methyl imidazole as a curing agent in order to investigate the effect of triazene moieties on polymeric properties for laser ablation application. The synthesized triazene monomer was characterized by analytical and spectroscopic methods, while the surface morphology of resist after laser ablation was visualized by optical laser scanning images and scanning electron microscopy. Thermogravimetrical investigations indicate the loss of nitrogen being the initial thermal decomposition step and exhibit sufficient stabilities for the requirements for laser ablation application. Fourier transform infra-red, nuclear magnetic resonance, and gas chromatography analyses showed the successful synthesis of triazene. The ablation results from the optical laser scanning images revealed that the etching depth could be controlled by varying the concentration of triazene monomer in the formulation of epoxy. The shear strength analysis revealed that that the shear strength increased with increasing the amount of triazene in the formulation of direct ablation sensitive resist. © 2014 The Korean Institute of Metals and Materials and Springer Science+Business Media Dordrecht.en
dc.publisherSpringer Natureen
dc.subjectepoxyen
dc.subjecthardneren
dc.subjectlaser ablationen
dc.subjecttriazeneen
dc.titleSynthesis and characterization of a novel laser ablation sensitive triazene incorporated epoxy resinen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalElectronic Materials Lettersen
dc.contributor.institutionDepartment of Polymer Science and Engineering, Sungkyunkwan University, Suwon, 440-746, South Koreaen
dc.contributor.institutionSchool of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, 440-746, South Koreaen
dc.contributor.institutionAdvanced Circuit-Interconnection Division, Samsung Electro-Mechanics Co. Ltd., Suwon, 440-746, South Koreaen
kaust.authorPatole, Archana S.en
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