N-Heterocyclic-Carbene-Catalysed Diastereoselective Vinylogous Mukaiyama/Michael Reaction of 2-(Trimethylsilyloxy)furan and Enones

Handle URI:
http://hdl.handle.net/10754/594176
Title:
N-Heterocyclic-Carbene-Catalysed Diastereoselective Vinylogous Mukaiyama/Michael Reaction of 2-(Trimethylsilyloxy)furan and Enones
Authors:
Wang, Ying; Du, Guang Fen; Xing, Fen; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Dai, Bin; He, Lin
Abstract:
N-heterocyclic carbenes have been utilised as highly efficient nucleophilic organocatalysts to mediate vinylogous Mukaiyama/Michael reactions of 2-(trimethylsilyloxy)furan with enones to afford γ-substituted butenolides in 44-99% yield with 3:1-32:1 diastereoselectivity. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC)
Citation:
Wang Y, Du G-F, Xing F, Huang K-W, Dai B, et al. (2015) N-Heterocyclic-Carbene-Catalysed Diastereoselective Vinylogous Mukaiyama/Michael Reaction of 2-(Trimethylsilyloxy)furan and Enones. Asian J Org Chem 4: 1362–1365. Available: http://dx.doi.org/10.1002/ajoc.201500348.
Publisher:
Wiley-Blackwell
Journal:
Asian Journal of Organic Chemistry
Issue Date:
15-Oct-2015
DOI:
10.1002/ajoc.201500348
Type:
Article
ISSN:
2193-5807
Sponsors:
Shihezi University[2012ZRKXJQ06]; National Natural Science Foundation of China[21262027, 21428302]
Appears in Collections:
Articles; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Yingen
dc.contributor.authorDu, Guang Fenen
dc.contributor.authorXing, Fenen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorDai, Binen
dc.contributor.authorHe, Linen
dc.date.accessioned2016-01-19T13:23:13Zen
dc.date.available2016-01-19T13:23:13Zen
dc.date.issued2015-10-15en
dc.identifier.citationWang Y, Du G-F, Xing F, Huang K-W, Dai B, et al. (2015) N-Heterocyclic-Carbene-Catalysed Diastereoselective Vinylogous Mukaiyama/Michael Reaction of 2-(Trimethylsilyloxy)furan and Enones. Asian J Org Chem 4: 1362–1365. Available: http://dx.doi.org/10.1002/ajoc.201500348.en
dc.identifier.issn2193-5807en
dc.identifier.doi10.1002/ajoc.201500348en
dc.identifier.urihttp://hdl.handle.net/10754/594176en
dc.description.abstractN-heterocyclic carbenes have been utilised as highly efficient nucleophilic organocatalysts to mediate vinylogous Mukaiyama/Michael reactions of 2-(trimethylsilyloxy)furan with enones to afford γ-substituted butenolides in 44-99% yield with 3:1-32:1 diastereoselectivity. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.description.sponsorshipShihezi University[2012ZRKXJQ06]en
dc.description.sponsorshipNational Natural Science Foundation of China[21262027, 21428302]en
dc.publisherWiley-Blackwellen
dc.subject2-(trimethylsilyloxy)furanen
dc.subjectButenolidesen
dc.subjectEnonesen
dc.subjectN-heterocyclic carbenesen
dc.subjectVinylogous Mukaiyama/Michael reactionen
dc.titleN-Heterocyclic-Carbene-Catalysed Diastereoselective Vinylogous Mukaiyama/Michael Reaction of 2-(Trimethylsilyloxy)furan and Enonesen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalAsian Journal of Organic Chemistryen
dc.contributor.institutionSchool of Chemistry and Chemical Engineering; Shihezi University; Shihezi, Xinjiang Uygur Autonomous Region P. R. Chinaen
dc.contributor.institutionLaboratory of Materials-Oriented Chemical Engineering of; Xinjiang Uygur Autonomous Region; Shihezi, Xinjiang Uygur Autonomous Region P. R. Chinaen
kaust.authorHuang, Kuo-Weien
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