Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer

Handle URI:
http://hdl.handle.net/10754/594090
Title:
Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer
Authors:
Bukhriakov, Konstantin; Mugemana, Clement; Vu, Khanh B.; Rodionov, Valentin
Abstract:
An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst. © 2015 American Chemical Society.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
Bukhryakov KV, Mugemana C, Vu KB, Rodionov VO (2015) Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer. Organic Letters 17: 4826–4829. Available: http://dx.doi.org/10.1021/acs.orglett.5b02388.
Publisher:
American Chemical Society (ACS)
Journal:
Organic Letters
Issue Date:
2-Oct-2015
DOI:
10.1021/acs.orglett.5b02388
PubMed ID:
26397957
Type:
Article
ISSN:
1523-7060; 1523-7052
Sponsors:
King Abdullah University of Science and Technology
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorBukhriakov, Konstantinen
dc.contributor.authorMugemana, Clementen
dc.contributor.authorVu, Khanh B.en
dc.contributor.authorRodionov, Valentinen
dc.date.accessioned2016-01-19T13:21:23Zen
dc.date.available2016-01-19T13:21:23Zen
dc.date.issued2015-10-02en
dc.identifier.citationBukhryakov KV, Mugemana C, Vu KB, Rodionov VO (2015) Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer. Organic Letters 17: 4826–4829. Available: http://dx.doi.org/10.1021/acs.orglett.5b02388.en
dc.identifier.issn1523-7060en
dc.identifier.issn1523-7052en
dc.identifier.pmid26397957en
dc.identifier.doi10.1021/acs.orglett.5b02388en
dc.identifier.urihttp://hdl.handle.net/10754/594090en
dc.description.abstractAn approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst. © 2015 American Chemical Society.en
dc.description.sponsorshipKing Abdullah University of Science and Technologyen
dc.publisherAmerican Chemical Society (ACS)en
dc.titlePalladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymeren
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalOrganic Lettersen
kaust.authorBukhriakov, Konstantinen
kaust.authorMugemana, Clementen
kaust.authorVu, Khanh B.en
kaust.authorRodionov, Valentinen
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