Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst

Handle URI:
http://hdl.handle.net/10754/594080
Title:
Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst
Authors:
Mazoyer, Etienne; Merle, Nicolas; Mallmann, Aimery De; Basset, Jean-Marie ( 0000-0003-3166-8882 ) ; Berrier, Elise; Delevoye, Laurent; Paul, Jean Franois; Nicholas, Christopher P.; Gauvin, Régis M.; Taoufik, Mostafa
Abstract:
A well-defined, silica-supported tungsten oxo alkyl species prepared by the surface organometallic chemistry approach displays high and sustained activity in propene metathesis. Remarkably, its catalytic performances outpace those of the parent imido derivative, underlining the importance of the oxo ligand in the design of robust catalysts. © 2010 The Royal Society of Chemistry.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Mazoyer E, Merle N, Mallmann A de, Basset J-M, Berrier E, et al. (2010) Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst. Chem Commun 46: 8944. Available: http://dx.doi.org/10.1039/c0cc02507k.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chemical Communications
Issue Date:
2010
DOI:
10.1039/c0cc02507k
PubMed ID:
20981359
Type:
Article
ISSN:
1359-7345; 1364-548X
Sponsors:
We thank the CNRS, MNESR and the TGE RMN THC Fr3050 for financial support, Julien Trebosc for his assistance with NMR spectroscopy and Marcel Wesolek for helpful discussions. E. Mazoyer thanks UOP for a graduate fellowship.
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorMazoyer, Etienneen
dc.contributor.authorMerle, Nicolasen
dc.contributor.authorMallmann, Aimery Deen
dc.contributor.authorBasset, Jean-Marieen
dc.contributor.authorBerrier, Eliseen
dc.contributor.authorDelevoye, Laurenten
dc.contributor.authorPaul, Jean Franoisen
dc.contributor.authorNicholas, Christopher P.en
dc.contributor.authorGauvin, Régis M.en
dc.contributor.authorTaoufik, Mostafaen
dc.date.accessioned2016-01-19T13:21:07Zen
dc.date.available2016-01-19T13:21:07Zen
dc.date.issued2010en
dc.identifier.citationMazoyer E, Merle N, Mallmann A de, Basset J-M, Berrier E, et al. (2010) Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst. Chem Commun 46: 8944. Available: http://dx.doi.org/10.1039/c0cc02507k.en
dc.identifier.issn1359-7345en
dc.identifier.issn1364-548Xen
dc.identifier.pmid20981359en
dc.identifier.doi10.1039/c0cc02507ken
dc.identifier.urihttp://hdl.handle.net/10754/594080en
dc.description.abstractA well-defined, silica-supported tungsten oxo alkyl species prepared by the surface organometallic chemistry approach displays high and sustained activity in propene metathesis. Remarkably, its catalytic performances outpace those of the parent imido derivative, underlining the importance of the oxo ligand in the design of robust catalysts. © 2010 The Royal Society of Chemistry.en
dc.description.sponsorshipWe thank the CNRS, MNESR and the TGE RMN THC Fr3050 for financial support, Julien Trebosc for his assistance with NMR spectroscopy and Marcel Wesolek for helpful discussions. E. Mazoyer thanks UOP for a graduate fellowship.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleDevelopment of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalysten
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalChemical Communicationsen
dc.contributor.institutionUniversité Lyon 1, Institut de Chimie Lyon, CNRS, UMR 5265 C2P2, LCOMS, Bât. 308 F 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne Cedex, Franceen
dc.contributor.institutionUniversité Lille Nord de France, CNRS UMR8181, UCCS USTL, F-59655 Villeneuve d'Ascq, Franceen
dc.contributor.institutionExploratory Catalysis Research, UOP LLC, Honeywell Company, 25 East Algonquin Rd., Des Plaines, IL, United Statesen
kaust.authorBasset, Jean-Marieen

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