Supramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs

Handle URI:
http://hdl.handle.net/10754/593174
Title:
Supramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs
Authors:
Abdul Halim, Racha Ghassan ( 0000-0003-3660-7325 ) ; Shkurenko, Aleksander ( 0000-0001-7136-2277 ) ; Al Kordi, Mohamed; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
Three novel metal-organic frameworks (MOFs) were isolated upon reacting a heterofunctional ligand 4 (pyrimidin-5 yl)benzoic acid (4,5-pmbc) with mixed valence Cu(I,II) under solvothermal conditions. X-ray crystal structural analysis reveals that the first compound is a layered structure composed of one type of inorganic building block, dinuclear paddlewheel [Cu2(O2C–)4], which are linked through 4,5-pmbc ligands. The two other supramolecular isomers are composed of the same Cu(II) dinuclear paddlewheel and a dinuclear Cu2I2 cluster, which are linked via the 4,5-pmbc linkers to yield two different 3-periodic frameworks with underlying topologies related to lvt and nbo. The observed structural diversity in these structures is due to the distinct coordination modes of the two coordinating moieties (the carboxylate group on the phenyl ring and the N-donor atoms from the pyrimidine moiety).
KAUST Department:
Functional Materials Design, Discovery and Development (FMD3); Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division
Citation:
Supramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs 2016 Crystal Growth & Design
Publisher:
American Chemical Society (ACS)
Journal:
Crystal Growth & Design
Issue Date:
4-Jan-2016
DOI:
10.1021/acs.cgd.5b01307
Type:
Article
ISSN:
1528-7483; 1528-7505
Is Supplemented By:
AbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444725: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc1g; DOI:10.5517/cc1khc1g; HANDLE:http://hdl.handle.net/10754/624490; AbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444726: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc2h; DOI:10.5517/cc1khc2h; HANDLE:http://hdl.handle.net/10754/624491; AbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444727: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc3j; DOI:10.5517/cc1khc3j; HANDLE:http://hdl.handle.net/10754/624492
Additional Links:
http://pubs.acs.org/doi/10.1021/acs.cgd.5b01307
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorAbdul Halim, Racha Ghassanen
dc.contributor.authorShkurenko, Aleksanderen
dc.contributor.authorAl Kordi, Mohameden
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2016-01-10T10:04:54Zen
dc.date.available2016-01-10T10:04:54Zen
dc.date.issued2016-01-04en
dc.identifier.citationSupramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs 2016 Crystal Growth & Designen
dc.identifier.issn1528-7483en
dc.identifier.issn1528-7505en
dc.identifier.doi10.1021/acs.cgd.5b01307en
dc.identifier.urihttp://hdl.handle.net/10754/593174en
dc.description.abstractThree novel metal-organic frameworks (MOFs) were isolated upon reacting a heterofunctional ligand 4 (pyrimidin-5 yl)benzoic acid (4,5-pmbc) with mixed valence Cu(I,II) under solvothermal conditions. X-ray crystal structural analysis reveals that the first compound is a layered structure composed of one type of inorganic building block, dinuclear paddlewheel [Cu2(O2C–)4], which are linked through 4,5-pmbc ligands. The two other supramolecular isomers are composed of the same Cu(II) dinuclear paddlewheel and a dinuclear Cu2I2 cluster, which are linked via the 4,5-pmbc linkers to yield two different 3-periodic frameworks with underlying topologies related to lvt and nbo. The observed structural diversity in these structures is due to the distinct coordination modes of the two coordinating moieties (the carboxylate group on the phenyl ring and the N-donor atoms from the pyrimidine moiety).en
dc.language.isoenen
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/10.1021/acs.cgd.5b01307en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Crystal Growth & Design, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.cgd.5b01307.en
dc.titleSupramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifsen
dc.typeArticleen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalCrystal Growth & Designen
dc.eprint.versionPost-printen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorAbdul Halim, Racha Ghassanen
kaust.authorShkurenko, Aleksanderen
kaust.authorAl Kordi, Mohameden
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByAbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444725: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc1gen
dc.relation.isSupplementedByDOI:10.5517/cc1khc1gen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624490en
dc.relation.isSupplementedByAbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444726: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc2hen
dc.relation.isSupplementedByDOI:10.5517/cc1khc2hen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624491en
dc.relation.isSupplementedByAbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444727: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc3jen
dc.relation.isSupplementedByDOI:10.5517/cc1khc3jen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624492en
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