CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand

Handle URI:
http://hdl.handle.net/10754/593138
Title:
CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand
Authors:
Pasha, Fahran Ahmad; Bendjeriou-Sedjerari, Anissa; Abou-Hamad, Edy; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand 2016 Chem. Commun.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
Issue Date:
4-Jan-2016
DOI:
10.1039/C5CC08821F
Type:
Article
ISSN:
1359-7345; 1364-548X
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC08821F
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorPasha, Fahran Ahmaden
dc.contributor.authorBendjeriou-Sedjerari, Anissaen
dc.contributor.authorAbou-Hamad, Edyen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2016-01-10T10:06:32Zen
dc.date.available2016-01-10T10:06:32Zen
dc.date.issued2016-01-04en
dc.identifier.citationCO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand 2016 Chem. Commun.en
dc.identifier.issn1359-7345en
dc.identifier.issn1364-548Xen
dc.identifier.doi10.1039/C5CC08821Fen
dc.identifier.urihttp://hdl.handle.net/10754/593138en
dc.description.abstractDensity functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.en
dc.language.isoenen
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC08821Fen
dc.rightsArchived with thanks to Chem. Commun.en
dc.titleCO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface liganden
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalChem. Commun.en
dc.eprint.versionPost-printen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorPasha, Fahran Ahmaden
kaust.authorBendjeriou-Sedjerari, Anissaen
kaust.authorAbou-Hamad, Edyen
kaust.authorHuang, Kuo-Weien
kaust.authorBasset, Jean-Marieen
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