N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2

Handle URI:
http://hdl.handle.net/10754/592738
Title:
N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2
Authors:
Santoro, Orlando; Lazreg, Faïma; Minenkov, Yury; Cavallo, Luigi ( 0000-0002-1398-338X ) ; Cazin, Catherine S. J.
Abstract:
The N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(I) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)
Citation:
N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2 2015, 44 (41):18138 Dalton Trans.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Dalton Trans.
Issue Date:
30-Sep-2015
DOI:
10.1039/C5DT03506F
Type:
Article
ISSN:
1477-9226; 1477-9234
Additional Links:
http://xlink.rsc.org/?DOI=C5DT03506F
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorSantoro, Orlandoen
dc.contributor.authorLazreg, Faïmaen
dc.contributor.authorMinenkov, Yuryen
dc.contributor.authorCavallo, Luigien
dc.contributor.authorCazin, Catherine S. J.en
dc.date.accessioned2016-01-04T06:02:51Zen
dc.date.available2016-01-04T06:02:51Zen
dc.date.issued2015-09-30en
dc.identifier.citationN-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2 2015, 44 (41):18138 Dalton Trans.en
dc.identifier.issn1477-9226en
dc.identifier.issn1477-9234en
dc.identifier.doi10.1039/C5DT03506Fen
dc.identifier.urihttp://hdl.handle.net/10754/592738en
dc.description.abstractThe N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(I) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation.en
dc.language.isoenen
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://xlink.rsc.org/?DOI=C5DT03506Fen
dc.rightsArchived with thanks to Dalton Trans. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. http://creativecommons.org/licenses/by/3.0/en
dc.titleN-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2en
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalDalton Trans.en
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionEaStCHEM School of Chemistry, University of St Andrews, St Andrews, UKen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorMinenkov, Yuryen
kaust.authorCavallo, Luigien
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