MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum Based soc-MOF for CH4, O2 and CO2 Storage

Handle URI:
http://hdl.handle.net/10754/578792
Title:
MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum Based soc-MOF for CH4, O2 and CO2 Storage
Authors:
Alezi, Dalal ( 0000-0002-3462-1193 ) ; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Suetin, Mikhail ( 0000-0002-4570-8905 ) ; Bhatt, Prashant; Weselinski, Lukasz Jan ( 0000-0003-4516-2727 ) ; Solovyeva, Vera ( 0000-0003-1671-6794 ) ; Adil, Karim ( 0000-0002-3804-1065 ) ; Spanopoulos, Ioannis; Trikalitis, Pantelis N.; Emwas, Abdul-Hamid M.; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
The molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum based Metal-Organic Frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized, namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOF platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm3 (STP)/cm3 (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOF pore structure and functionality to the gas storage properties, to better understand the structure-properties relationship, we performed a molecular simulation study and evaluated the methane storage performance of Al-soc-MOF platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOF-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOF-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes in a wide range of pressure and temperature conditions.
KAUST Department:
Functional Materials Design, Discovery and Development (FMD3); Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division
Citation:
MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum Based soc-MOF for CH4, O2 and CO2 Storage 2015:150928030808008 Journal of the American Chemical Society
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
Issue Date:
28-Sep-2015
DOI:
10.1021/jacs.5b07053
Type:
Article
ISSN:
0002-7863; 1520-5126
Is Supplemented By:
Alezi, D., Belmabkhout, Y., Suyetin, M., Bhatt, P. M., Weseliński, Ł. J., Solovyeva, V., … Eddaoudi, M. (2015). CCDC 1432977: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1k342w; DOI:10.5517/cc1k342w; HANDLE:http://hdl.handle.net/10754/624477; Alezi, D., Belmabkhout, Y., Suyetin, M., Bhatt, P. M., Weseliński, Ł. J., Solovyeva, V., … Eddaoudi, M. (2015). CCDC 1432978: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1k343x; DOI:10.5517/cc1k343x; HANDLE:http://hdl.handle.net/10754/624478
Additional Links:
http://pubsdc3.acs.org/doi/10.1021/jacs.5b07053
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorAlezi, Dalalen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorSuetin, Mikhailen
dc.contributor.authorBhatt, Prashanten
dc.contributor.authorWeselinski, Lukasz Janen
dc.contributor.authorSolovyeva, Veraen
dc.contributor.authorAdil, Karimen
dc.contributor.authorSpanopoulos, Ioannisen
dc.contributor.authorTrikalitis, Pantelis N.en
dc.contributor.authorEmwas, Abdul-Hamid M.en
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2015-09-29T05:20:41Zen
dc.date.available2015-09-29T05:20:41Zen
dc.date.issued2015-09-28en
dc.identifier.citationMOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum Based soc-MOF for CH4, O2 and CO2 Storage 2015:150928030808008 Journal of the American Chemical Societyen
dc.identifier.issn0002-7863en
dc.identifier.issn1520-5126en
dc.identifier.doi10.1021/jacs.5b07053en
dc.identifier.urihttp://hdl.handle.net/10754/578792en
dc.description.abstractThe molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum based Metal-Organic Frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized, namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOF platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm3 (STP)/cm3 (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOF pore structure and functionality to the gas storage properties, to better understand the structure-properties relationship, we performed a molecular simulation study and evaluated the methane storage performance of Al-soc-MOF platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOF-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOF-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes in a wide range of pressure and temperature conditions.en
dc.language.isoenen
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubsdc3.acs.org/doi/10.1021/jacs.5b07053en
dc.rightsThis is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.en
dc.rights.urihttp://pubs.acs.org/page/policy/authorchoice_termsofuse.htmlen
dc.titleMOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum Based soc-MOF for CH4, O2 and CO2 Storageen
dc.typeArticleen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalJournal of the American Chemical Societyen
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorAlezi, Dalalen
kaust.authorBelmabkhout, Youssefen
kaust.authorSuetin, Mikhailen
kaust.authorBhatt, Prashanten
kaust.authorWeselinski, Lukasz Janen
kaust.authorSolovyeva, Veraen
kaust.authorAdil, Karimen
kaust.authorEmwas, Abdul-Hamid M.en
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByAlezi, D., Belmabkhout, Y., Suyetin, M., Bhatt, P. M., Weseliński, Ł. J., Solovyeva, V., … Eddaoudi, M. (2015). CCDC 1432977: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1k342wen
dc.relation.isSupplementedByDOI:10.5517/cc1k342wen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624477en
dc.relation.isSupplementedByAlezi, D., Belmabkhout, Y., Suyetin, M., Bhatt, P. M., Weseliński, Ł. J., Solovyeva, V., … Eddaoudi, M. (2015). CCDC 1432978: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1k343xen
dc.relation.isSupplementedByDOI:10.5517/cc1k343xen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624478en
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