Sequence-controlled polymerization guided by aryl-fluoroaryl π-stacking

Handle URI:
http://hdl.handle.net/10754/575819
Title:
Sequence-controlled polymerization guided by aryl-fluoroaryl π-stacking
Authors:
Mugemana, Clement; Almahdali, Sarah; Rodionov, Valentin
Abstract:
The ability to control monomer sequences is essential in macromolecular chemistry. Better sequence control leads to better control over macromolecular folding and self-assembly, which, in turn, would enable control over bulk properties (such as thermal behavior, conductivity and rigidity), as well as mimicking the properties of globular proteins. Here, we present a three-part synopsis of recent advances in research on sequence-controlled polymerization guided by aryl-perfluoroaryl π-π stacking of monomer pairs. We also show that for monomers that are capable of strong associative interactions, the classical reactivity ratio analysis based on Fineman-Ross/terminal reactivity models may lead to an imprecise determination of the monomer alternation mode. © 2014 American Chemical Society.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Publisher:
American Chemical Society (ACS)
Journal:
Sequence-Controlled Polymers: Synthesis, Self-Assembly, and Properties
Issue Date:
Jan-2014
DOI:
10.1021/bk-2014-1170.ch016
Type:
Book Chapter
ISSN:
00976156
ISBN:
9780841230019
Appears in Collections:
Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Chemical Science Program; KAUST Catalysis Center (KCC); Book Chapters

Full metadata record

DC FieldValue Language
dc.contributor.authorMugemana, Clementen
dc.contributor.authorAlmahdali, Sarahen
dc.contributor.authorRodionov, Valentinen
dc.date.accessioned2015-08-24T09:27:02Zen
dc.date.available2015-08-24T09:27:02Zen
dc.date.issued2014-01en
dc.identifier.isbn9780841230019en
dc.identifier.issn00976156en
dc.identifier.doi10.1021/bk-2014-1170.ch016en
dc.identifier.urihttp://hdl.handle.net/10754/575819en
dc.description.abstractThe ability to control monomer sequences is essential in macromolecular chemistry. Better sequence control leads to better control over macromolecular folding and self-assembly, which, in turn, would enable control over bulk properties (such as thermal behavior, conductivity and rigidity), as well as mimicking the properties of globular proteins. Here, we present a three-part synopsis of recent advances in research on sequence-controlled polymerization guided by aryl-perfluoroaryl π-π stacking of monomer pairs. We also show that for monomers that are capable of strong associative interactions, the classical reactivity ratio analysis based on Fineman-Ross/terminal reactivity models may lead to an imprecise determination of the monomer alternation mode. © 2014 American Chemical Society.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleSequence-controlled polymerization guided by aryl-fluoroaryl π-stackingen
dc.typeBook Chapteren
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.identifier.journalSequence-Controlled Polymers: Synthesis, Self-Assembly, and Propertiesen
kaust.authorMugemana, Clementen
kaust.authorAlmahdali, Sarahen
kaust.authorRodionov, Valentinen
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