Catalytic oxidation of light alkanes (C1-C4) by heteropoly compounds

Handle URI:
http://hdl.handle.net/10754/566081
Title:
Catalytic oxidation of light alkanes (C1-C4) by heteropoly compounds
Authors:
Sun, Miao; Zhang, Jizhe; Putaj, Piotr; Caps, Valerie; Lefèbvre, Frédéric; Pelletier, Jeremie ( 0000-0002-4709-4898 ) ; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
Heteropoly compounds (HPC) have revealed their potential to generate catalyst for selectively converting light alkanes to oxygenated products. There are various structures in which they are active the primary structure being that of the heteropolyanion itself, the secondary structure is the three-dimensional arrangements of polyanions, and the tertiary structure representing the manner in which the secondary structure assembles into solid particles. There are also a huge variety of elements inside the HPA. The heteropoly acids can have acidity, which varies dramatically depending on composition. This complexity of situation makes it very difficult to really have a predictive vision of their ability to activate and functionalize alkanes. However, a large amount of data reported suggests that the initial formula of the precatalyst is pivotal to direct the selectivity of the reaction toward different oxygenates. Inclusion of alternative transition metal atoms as addenda is highly influential with iron, vanadium, and antimony being particularly outstanding.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC)
Publisher:
American Chemical Society (ACS)
Journal:
Chemical Reviews
Issue Date:
22-Jan-2014
DOI:
10.1021/cr300302b
Type:
Article
ISSN:
00092665
Appears in Collections:
Articles; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorSun, Miaoen
dc.contributor.authorZhang, Jizheen
dc.contributor.authorPutaj, Piotren
dc.contributor.authorCaps, Valerieen
dc.contributor.authorLefèbvre, Frédéricen
dc.contributor.authorPelletier, Jeremieen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-12T09:27:30Zen
dc.date.available2015-08-12T09:27:30Zen
dc.date.issued2014-01-22en
dc.identifier.issn00092665en
dc.identifier.doi10.1021/cr300302ben
dc.identifier.urihttp://hdl.handle.net/10754/566081en
dc.description.abstractHeteropoly compounds (HPC) have revealed their potential to generate catalyst for selectively converting light alkanes to oxygenated products. There are various structures in which they are active the primary structure being that of the heteropolyanion itself, the secondary structure is the three-dimensional arrangements of polyanions, and the tertiary structure representing the manner in which the secondary structure assembles into solid particles. There are also a huge variety of elements inside the HPA. The heteropoly acids can have acidity, which varies dramatically depending on composition. This complexity of situation makes it very difficult to really have a predictive vision of their ability to activate and functionalize alkanes. However, a large amount of data reported suggests that the initial formula of the precatalyst is pivotal to direct the selectivity of the reaction toward different oxygenates. Inclusion of alternative transition metal atoms as addenda is highly influential with iron, vanadium, and antimony being particularly outstanding.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleCatalytic oxidation of light alkanes (C1-C4) by heteropoly compoundsen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalChemical Reviewsen
dc.contributor.institutionResearch and Development Center, Saudi Aramco Oil Company, Dhahran 31311, Saudi Arabiaen
dc.contributor.institutionLaboratoire de Chimie Organométallique de Surface, CPE Lyon, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne, Franceen
kaust.authorZhang, Jizheen
kaust.authorCaps, Valerieen
kaust.authorPelletier, Jeremieen
kaust.authorBasset, Jean-Marieen
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