Stabilization of 200-atom platinum nanoparticles by organosilane fragments

Handle URI:
http://hdl.handle.net/10754/566035
Title:
Stabilization of 200-atom platinum nanoparticles by organosilane fragments
Authors:
Pelzer, Katrin; Hävecker, Michael; Boualleg, Malika; Candy, Jean Pierre; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
Three's a charm: Platinum nanoparticles of 2 nm diameter and containing approximately 200 atoms covered with n-octylsilyl groups (see picture, right; Pt blue, Si red, C gray, H turquoise) form when [Pt(dba)2] (dba=dibenzylideneacetone) decomposes in the presence of n-octylsilane. The particles adopt a cuboctahedral structure with an edge length of three atoms. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie International Edition
Issue Date:
19-Apr-2011
DOI:
10.1002/anie.201008209
Type:
Article
ISSN:
14337851
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorPelzer, Katrinen
dc.contributor.authorHävecker, Michaelen
dc.contributor.authorBoualleg, Malikaen
dc.contributor.authorCandy, Jean Pierreen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-12T09:00:26Zen
dc.date.available2015-08-12T09:00:26Zen
dc.date.issued2011-04-19en
dc.identifier.issn14337851en
dc.identifier.doi10.1002/anie.201008209en
dc.identifier.urihttp://hdl.handle.net/10754/566035en
dc.description.abstractThree's a charm: Platinum nanoparticles of 2 nm diameter and containing approximately 200 atoms covered with n-octylsilyl groups (see picture, right; Pt blue, Si red, C gray, H turquoise) form when [Pt(dba)2] (dba=dibenzylideneacetone) decomposes in the presence of n-octylsilane. The particles adopt a cuboctahedral structure with an edge length of three atoms. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.publisherWiley-Blackwellen
dc.subjectheterogeneous catalysisen
dc.subjectnanoparticlesen
dc.subjectplatinumen
dc.titleStabilization of 200-atom platinum nanoparticles by organosilane fragmentsen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalAngewandte Chemie International Editionen
kaust.authorBasset, Jean-Marieen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.