Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization

Handle URI:
http://hdl.handle.net/10754/566032
Title:
Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization
Authors:
Popoff, Nicolas; Espinas, Jeff; Gouré, Eric; Boyron, Olivier; Le Roux, Erwan; Basset, Jean-Marie ( 0000-0003-3166-8882 ) ; Gauvin, Régis M.; De Mallmann, Aimery; Taoufik, Mostafa
Abstract:
Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KAUST Department:
Chemical Science Program; KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Publisher:
Wiley-Blackwell
Journal:
Macromolecular Rapid Communications
Issue Date:
22-Sep-2011
DOI:
10.1002/marc.201100477
PubMed ID:
21948353
Type:
Article
ISSN:
10221336
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorPopoff, Nicolasen
dc.contributor.authorEspinas, Jeffen
dc.contributor.authorGouré, Ericen
dc.contributor.authorBoyron, Olivieren
dc.contributor.authorLe Roux, Erwanen
dc.contributor.authorBasset, Jean-Marieen
dc.contributor.authorGauvin, Régis M.en
dc.contributor.authorDe Mallmann, Aimeryen
dc.contributor.authorTaoufik, Mostafaen
dc.date.accessioned2015-08-12T09:00:17Zen
dc.date.available2015-08-12T09:00:17Zen
dc.date.issued2011-09-22en
dc.identifier.issn10221336en
dc.identifier.pmid21948353en
dc.identifier.doi10.1002/marc.201100477en
dc.identifier.urihttp://hdl.handle.net/10754/566032en
dc.description.abstractSilica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.publisherWiley-Blackwellen
dc.subjectactivationen
dc.subjectorganometallic catalystsen
dc.subjectpolyethyleneen
dc.subjecttransition metal chemistryen
dc.titleShifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerizationen
dc.typeArticleen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalMacromolecular Rapid Communicationsen
kaust.authorEspinas, Jeffen
kaust.authorBasset, Jean-Marieen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.