Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-δ (x = 0.05–0.20) as a pigment

Handle URI:
http://hdl.handle.net/10754/565798
Title:
Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-δ (x = 0.05–0.20) as a pigment
Authors:
Stojmenović, Marija; Milenković, Maja C.; Banković, Predrag T.; Zunic, Milan ( 0000-0002-0416-805X ) ; Gulicovski, Jelena J.; Pantić, Jelena R.; Bošković, Snežana B.
Abstract:
Ceramic pigments based on cerium oxide were synthesized by self–propagating room temperature method and their color properties were assessed from the viewpoint of potential environmentally nontoxic pink pigments. Thermal stabilities of the pigments were examined at 600, 900 and 1200 ºC. According to X–ray powder diffraction and Raman spectroscopy results, all obtained pigments were single–phase solid solutions of cerium oxide, independent of the concentration of dopants. The X–ray analysis showed that the crystallites were of nanometric dimensions, as recorded and by transmission electron microscopy analysis. Color characteristics of solid solutions, which depended on concentracion erbium ions and calcination temperature, and their position in the chromaticity diagram were studied by ultraviolet–visible spectrophotometry, which confirmed potential application of environmentally friendly pigments of desired color. The color efficiency of pigments was also evaluated by colorimetric analysis.
KAUST Department:
Physical Sciences and Engineering (PSE) Division
Citation:
Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-δ (x = 0.05–0.20) as a pigment 2015 Dyes and Pigments
Publisher:
Elsevier BV
Journal:
Dyes and Pigments
Issue Date:
31-Jul-2015
DOI:
10.1016/j.dyepig.2015.07.030
Type:
Article
ISSN:
01437208
Additional Links:
http://linkinghub.elsevier.com/retrieve/pii/S0143720815002983
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorStojmenović, Marijaen
dc.contributor.authorMilenković, Maja C.en
dc.contributor.authorBanković, Predrag T.en
dc.contributor.authorZunic, Milanen
dc.contributor.authorGulicovski, Jelena J.en
dc.contributor.authorPantić, Jelena R.en
dc.contributor.authorBošković, Snežana B.en
dc.date.accessioned2015-08-10T12:23:53Zen
dc.date.available2015-08-10T12:23:53Zen
dc.date.issued2015-07-31en
dc.identifier.citationInfluence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-δ (x = 0.05–0.20) as a pigment 2015 Dyes and Pigmentsen
dc.identifier.issn01437208en
dc.identifier.doi10.1016/j.dyepig.2015.07.030en
dc.identifier.urihttp://hdl.handle.net/10754/565798en
dc.description.abstractCeramic pigments based on cerium oxide were synthesized by self–propagating room temperature method and their color properties were assessed from the viewpoint of potential environmentally nontoxic pink pigments. Thermal stabilities of the pigments were examined at 600, 900 and 1200 ºC. According to X–ray powder diffraction and Raman spectroscopy results, all obtained pigments were single–phase solid solutions of cerium oxide, independent of the concentration of dopants. The X–ray analysis showed that the crystallites were of nanometric dimensions, as recorded and by transmission electron microscopy analysis. Color characteristics of solid solutions, which depended on concentracion erbium ions and calcination temperature, and their position in the chromaticity diagram were studied by ultraviolet–visible spectrophotometry, which confirmed potential application of environmentally friendly pigments of desired color. The color efficiency of pigments was also evaluated by colorimetric analysis.en
dc.language.isoenen
dc.publisherElsevier BVen
dc.relation.urlhttp://linkinghub.elsevier.com/retrieve/pii/S0143720815002983en
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in Dyes and Pigments. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Dyes and Pigments, 31 July 2015. DOI: 10.1016/j.dyepig.2015.07.030en
dc.subjectRare earth pigmentsen
dc.subjectNon–toxic pigmentsen
dc.subjectOptical propertiesen
dc.subjectBand gapen
dc.subjectColorimetricen
dc.titleInfluence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-δ (x = 0.05–0.20) as a pigmenten
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalDyes and Pigmentsen
dc.eprint.versionPost-printen
dc.contributor.institutionUniversity of Belgrade–Institute of Nuclear Sciences Vinča, Mike Petrovića Alasa 12–14, Belgrade, Serbiaen
dc.contributor.institutionUniversity of Belgrade–Faculty of Physical Chemistry, Studentski trg 12, 11000 Belgrade, Serbiaen
dc.contributor.institutionUniversity of Belgrade–Institute of Chemistry, Technology and Metallurgy–Center for Catalysis and Chemical Engineering, Njegoševa 12, 11000 Belgrade, Serbiaen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorZunic, Milanen
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