A combined salt-hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performance

Handle URI:
http://hdl.handle.net/10754/564180
Title:
A combined salt-hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performance
Authors:
Bhandari, Nidhi; Dua, Rubal; Estévez, Luis Antonio; Sahore, Ritu; Giannelis, Emmanuel P.
Abstract:
A new approach, based on a combination of salt and hard templating for producing multi-modal porous carbons is demonstrated. The hard template, silica nanoparticles, generate mesopores (∼22 nm), and in some cases borderline-macropores (∼64 nm), resulting in high pore volume (∼3.9 cm3/g) while the salt template, zinc chloride, generates borderline-mesopores (∼2 nm), thus imparting high surface area (∼2100 m2/g). The versatility of the proposed synthesis technique is demonstrated using: (i) dual salt templates with hard template resulting in magnetic, nanostructured-clay embedded (∼27% clay content), high surface area (∼1527 m2/g) bimodal carbons (∼2 and 70 nm pores), (ii) multiple hard templates with salt template resulting in tri-modal carbons (∼2, 12 and 28 nm pores), (iii) low temperature (450 °C) synthesis of bimodal carbons afforded by the presence of hygroscopic salt template, (iv) easy coupling with physical activation approaches. A selected set of thus synthesized carbons were used to evaluate, for the first time, the simultaneous effects of carbon porosity and pressure applied during electrode fabrication on EDLC performance. Electrode pressing was found to be more favorable for carbons containing hard-templated mesopores (∼87% capacitance retention at current density of 40 A/g) as compared to those without (∼54% capacitance retention). © 2015 Elsevier Ltd. All rights reserved.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; Environmental Science and Engineering Program; Water Desalination and Reuse Research Center (WDRC)
Publisher:
Elsevier BV
Journal:
Carbon
Issue Date:
Jun-2015
DOI:
10.1016/j.carbon.2015.01.039
Type:
Article
ISSN:
00086223
Sponsors:
This work was supported in part by Award no. KUS-C1-018-02 made by King Abdullah University of Science and Technology (KAUST), by the Energy Materials Center at Cornell (EMC2) an Energy Frontiers Research Center funded by the U.S. Department of Energy and by the National Science Foundation (NSF) Grassroots GK-12 program (Award no. DGE 1045513). The authors thank Dr. Nini Wei and Dr. Qingxiao Wang (KAUST Imaging and Characterization Core Lab) for their help with the TEM and EDX investigation.
Appears in Collections:
Articles; Environmental Science and Engineering Program; Water Desalination and Reuse Research Center (WDRC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorBhandari, Nidhien
dc.contributor.authorDua, Rubalen
dc.contributor.authorEstévez, Luis Antonioen
dc.contributor.authorSahore, Rituen
dc.contributor.authorGiannelis, Emmanuel P.en
dc.date.accessioned2015-08-03T12:35:22Zen
dc.date.available2015-08-03T12:35:22Zen
dc.date.issued2015-06en
dc.identifier.issn00086223en
dc.identifier.doi10.1016/j.carbon.2015.01.039en
dc.identifier.urihttp://hdl.handle.net/10754/564180en
dc.description.abstractA new approach, based on a combination of salt and hard templating for producing multi-modal porous carbons is demonstrated. The hard template, silica nanoparticles, generate mesopores (∼22 nm), and in some cases borderline-macropores (∼64 nm), resulting in high pore volume (∼3.9 cm3/g) while the salt template, zinc chloride, generates borderline-mesopores (∼2 nm), thus imparting high surface area (∼2100 m2/g). The versatility of the proposed synthesis technique is demonstrated using: (i) dual salt templates with hard template resulting in magnetic, nanostructured-clay embedded (∼27% clay content), high surface area (∼1527 m2/g) bimodal carbons (∼2 and 70 nm pores), (ii) multiple hard templates with salt template resulting in tri-modal carbons (∼2, 12 and 28 nm pores), (iii) low temperature (450 °C) synthesis of bimodal carbons afforded by the presence of hygroscopic salt template, (iv) easy coupling with physical activation approaches. A selected set of thus synthesized carbons were used to evaluate, for the first time, the simultaneous effects of carbon porosity and pressure applied during electrode fabrication on EDLC performance. Electrode pressing was found to be more favorable for carbons containing hard-templated mesopores (∼87% capacitance retention at current density of 40 A/g) as compared to those without (∼54% capacitance retention). © 2015 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipThis work was supported in part by Award no. KUS-C1-018-02 made by King Abdullah University of Science and Technology (KAUST), by the Energy Materials Center at Cornell (EMC2) an Energy Frontiers Research Center funded by the U.S. Department of Energy and by the National Science Foundation (NSF) Grassroots GK-12 program (Award no. DGE 1045513). The authors thank Dr. Nini Wei and Dr. Qingxiao Wang (KAUST Imaging and Characterization Core Lab) for their help with the TEM and EDX investigation.en
dc.publisherElsevier BVen
dc.titleA combined salt-hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performanceen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentEnvironmental Science and Engineering Programen
dc.contributor.departmentWater Desalination and Reuse Research Center (WDRC)en
dc.identifier.journalCarbonen
dc.contributor.institutionDepartment of Materials Science and Engineering, Cornell UniversityIthaca, NY, United Statesen
kaust.authorDua, Rubalen
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